System and method for quality management utilizing barcode indicators

ABSTRACT

A quality management system for products including a multiplicity of barcoded quality indicators each operative to provide a machine-readable indication of exceedance of at least one threshold by at least one product quality affecting parameter, a barcode indicator reader operative to read the barcoded quality indicators and to provide output indications, the barcoded quality indicators being readable by the barcode indicator reader at all times after first becoming readable, including times prior to, during and immediately following exceedance of the at least one threshold by the at least one product quality affecting parameter, and a product type responsive indication interpreter operative to receive the output indications and to provide human sensible, product quality status outputs.

REFERENCE TO RELATED APPLICATIONS

Reference is made to PCT Patent Application No. PCT/IL07/000547, filedMay 6, 2007 and entitled “A System And Method For Improved QualityManagement In A Product Logistic Chain”, to PCT Patent Application No.PCT/IL07/01411, filed Nov. 14, 2007 and entitled “A System And MethodFor Quality Management Utilizing Barcode Indicators”, and to U.S.Provisional Application No. 61/131,644, filed Jun. 10, 2008 and entitled“A System And Method For Quality Management Utilizing BarcodeIndicators”, the disclosures of which are hereby incorporated byreference.

Priority is hereby claimed under 37 CFR 1.78(a) (1) and (2)(i) from PCTPatent Application No. PCT/IL07/01411, filed Nov. 14, 2007 and entitled“A System And Method For Quality Management Utilizing BarcodeIndicators”, and under 37 CFR 1.78(a) (4) and (5)(i) from U.S.Provisional Application No. 61/131,644, filed Jun. 10, 2008 and entitled“A System And Method For Quality Management Utilizing BarcodeIndicators”.

FIELD OF THE INVENTION

The present invention relates to quality management systems andmethodologies and to indicators useful in such systems andmethodologies.

BACKGROUND OF THE INVENTION

The following U.S. Patents relate generally to the subject matter of thepresent application: U.S. Pat. Nos. 6,758,397; 6,009,400, 6,685,094 andRE 39,226.

SUMMARY OF THE INVENTION

The present invention seeks to provide improved quality managementsystems and methodologies as well as indicators useful in such systemsand methodologies.

There is thus provided in accordance with a preferred embodiment of thepresent invention a quality management system for products including amultiplicity of barcoded quality indicators each operative to provide amachine-readable indication of exceedance of at least one threshold byat least one product quality affecting parameter, a barcode indicatorreader operative to read the barcoded quality indicators and to provideoutput indications, the barcoded quality indicators being readable bythe barcode indicator reader at all times after first becoming readable,including times prior to, during and immediately following exceedance ofthe at least one threshold by the at least one product quality affectingparameter, and a product type responsive indication interpreteroperative to receive the output indications and to provide humansensible, product quality status outputs.

Preferably, the barcoded quality indicators include linear barcodes.

Preferably, each of the multiplicity of barcoded quality indicatorsprovides a first machine-readable indication prior to the exceedance ofthe at least one threshold and a second machine-readable indication,different from the first machine-readable indication, following theexceedance of the at least one threshold. Additionally, the first andthe second machine-readable indications have identical checksum digitsand differ by two digits thereof, and the first and the secondmachine-readable indications have checksum integrity under an EAN/UPCchecksum system. Alternatively, the first and the secondmachine-readable indications have different checksum digits and differby at least one digit thereof and the first and the secondmachine-readable indications have checksum integrity under an EAN/UPCchecksum system. Additionally or alternatively, during exceedance of thethreshold the barcoded quality indicators simultaneously provide twomachine-readable indications, corresponding to the firstmachine-readable indication and to the second machine-readableindication.

Preferably, the product type responsive indication interpreter isprogrammable to prefer an exceedance indication over a subsequently readnon-exceedance indication for the same threshold.

Preferably, one of the at least one product quality affecting parametersis time.

Preferably, the quality indicators are operative to provide indicationsof exceedance of several different thresholds and an indication ofexceedance may be provided for one threshold at a time when anindication of exceedance is not provided for another threshold.

Preferably, the quality indicators are operative to provide themachine-readable indication only following actuation thereof.Alternatively, the quality indicators are operative to provide themachine-readable indication only upon activation thereof which occursautomatically a predetermined time following manufacture or actuationthereof. Additionally, prior to the actuation the quality indicators arein a first visible state and following the actuation the qualityindicators may be in a second visible state, different from the firstvisible state, and the indicators are machine-readable at least in thesecond visible state. Additionally, the indicators are notmachine-readable when the indicators are in the first visible state.Alternatively, the indicators are machine-readable when the indicatorsare in the first visible state.

Preferably, the product type responsive indication interpreter isfurther operative to receive an input in addition to the outputindications, the input being necessary to provide quality, productquality status outputs. Additionally, the indication interpreter formspart of or is otherwise connected to a computer including a productstatus table useful to provide product quality status outputs based onthe output indications and the input. Additionally, the input includesproduct-related parameters.

There is also provided in accordance with another preferred embodimentof the present invention a barcoded quality indicator operative toprovide a machine-readable indication of exceedance of at least onethreshold by at least one product quality affecting parameter, thebarcoded quality indicator being readable by a barcode indicator readerat all times after first becoming readable, including times prior to,during and immediately following exceedance of the at least onethreshold by the at least one product quality affecting parameter.

Preferably, the barcoded quality indicator includes linear barcodes.

Preferably, the barcoded quality indicator provides a firstmachine-readable indication prior to the exceedance of the at least onethreshold and a second machine-readable indication, different from thefirst machine-readable indication, following the exceedance of the atleast one threshold. Additionally, the first and the secondmachine-readable indications have identical checksum digits and differby two digits thereof, and the first and the second machine-readableindications have checksum integrity under an EAN/UPC checksum system.Alternatively, the first and the second machine-readable indicationshave different checksum digits and differ by at least one digit thereofand the first and the second machine-readable indications have checksumintegrity under an EAN/UPC checksum system. Additionally oralternatively, during exceedance of the threshold the barcoded qualityindicator simultaneously provides two machine-readable indications,corresponding to the first machine-readable indication and to the secondmachine-readable indication.

Preferably, one of the at least one product quality affecting parametersis time.

There is additionally provided in accordance with yet another preferredembodiment of the present invention a method for providing qualitymanagement for products including employing a multiplicity of barcodedquality indicators each operative to provide a machine-readableindication of exceedance of at least one threshold by at least oneproduct quality affecting parameter, reading the barcoded qualityindicators and providing output indications therefrom, the barcodedquality indicators being readable at all times after first becomingreadable, including times prior to, during and immediately followingexceedance of the at least one threshold by the at least one productquality affecting parameter, receiving the output indications, andinterpreting the output indications to provide human sensible, productquality status outputs.

Preferably, the barcoded quality indicators include linear barcodes.

Preferably, each of the multiplicity of barcoded quality indicatorsprovides a first machine-readable indication prior to the exceedance ofthe at least one threshold and a second machine-readable indication,different from the first machine-readable indication, following theexceedance of the at least one threshold. Additionally, the first andthe second machine-readable indications have identical checksum digitsand differ by two digits thereof, and the first and the secondmachine-readable indications have checksum integrity under an EAN/UPCchecksum system. Alternatively, the first and the secondmachine-readable indications have different checksum digits and differby at least one digit thereof and the first and the secondmachine-readable indications have checksum integrity under an EAN/UPCchecksum system. Additionally or alternatively, during exceedance of thethreshold the barcoded quality indicators simultaneously provide twomachine-readable indications, corresponding to the firstmachine-readable indication and to the second machine-readableindication.

Preferably, one of the at least one product quality affecting parametersis time.

There is also provided in accordance with another preferred embodimentof the present invention a quality management system including amultiplicity of barcoded quality indicators each operative to provide amachine-readable indication of exceedance of at least one threshold byat least one product quality affecting parameter, each of themultiplicity of barcoded quality indicators including a barcodeincluding black areas and transparent areas arranged along a barcodeaxis, at least one colorable element at least partially underlying thetransparent areas, and at least one coloring agent adapted to color theat least one colorable element in response to exceedance of the at leastone threshold, the at least one coloring agent passing along a pathwayto the at least one colorable element in a time corresponding to thethreshold, the pathway being configured such that the coloring agentprogressively colors the colorable element in a direction generallyperpendicular with respect to the barcode axis, thereby enabling thebarcode to be readable while the colorable element is beingprogressively colored.

Preferably, the barcoded quality indicators include linear barcodes.

Preferably, each of the multiplicity of barcoded quality indicatorsprovides a first machine-readable indication prior to the exceedance ofthe at least one threshold and a second machine-readable indication,different from the first machine-readable indication, following theexceedance of the at least one threshold. Additionally, duringexceedance of the threshold the barcoded quality indicatorssimultaneously provide two machine-readable indications, correspondingto the first machine-readable indication and to the secondmachine-readable indication. Additionally, during exceedance of thethreshold the coloring agent colors part of the colorable element suchthat the first machine-readable indication is provided by portions ofthe transparent areas lying above areas of the colorable element notcolored by the coloring agent read together with areas of the barcodenot lying above the colorable element, and the second machine-readableindication is provided by portions of the transparent areas lying aboveareas of the colorable element colored by the coloring agent readtogether with areas of the barcode not lying above the colorableelement.

Additionally or alternatively, each of the multiplicity of qualityindicators further includes a pull strip, the pull strip being suitableto prevent the passage of solvents and coloring agents therethroughbefore removal thereof, and removal of the pull strip actuates theindicators.

Preferably, each of the multiplicity of quality indicators furtherincludes an activation delay layer dissolvable by a solvent, theactivation delay layer being suitable to prevent the passage of coloringagents and solvents therethrough before dissolution thereof and theindicators are not activated until dissolution of the delay layer.

There is additionally provided in accordance with yet another preferredembodiment of the present invention a quality management system forproducts including a first multiplicity of individual package specificbarcoded quality indicators each operative to provide a machine-readableindication of exceedance of at least one threshold by at least oneproduct quality affecting parameter of an individual package, a secondmultiplicity of outer package specific barcoded quality indicators eachoperative to provide a machine-readable indication of exceedance of atleast one threshold by at least one product quality affecting parameterof an outer package containing a plurality of the individual packages, abarcode indicator reader operative to read the indicators and to provideoutput indications, and a product type responsive indication interpreteroperative to receive the output indications and to provide humansensible, product quality status outputs.

Preferably, the individual package specific barcoded quality indicatorsand the outer package specific barcoded quality indicators includelinear barcodes.

Preferably, the outer package specific indicators indicate theexceedance of thresholds which correspond to the thresholds for whichindication of exceedance is provided by the individual package specificindicators. Additionally, indication of exceedance may be provided bythe outer package specific indicators associated with outer packageseven when indication of exceedance is not provided by the individualpackage specific indicators attached to the individual packagescontained therein. Additionally, indication of exceedance is notprovided by the individual package specific indicators associated withindividual packages if an indication of exceedance was not provided bythe outer package specific indicators associated with the outer packagescontaining them. Alternatively, the thresholds for which indication ofexceedance is provided by the outer package specific indicatorscorrespond to an operative range different from the operative range towhich the thresholds for which indication of exceedance is provided bythe individual package specific indicators correspond.

BRIEF DESCRIPTION OF THE DRAWINGS

The present invention will be understood and appreciated more fully fromthe following detailed description, taken in conjunction with thedrawings in which:

FIGS. 1A-1F together are a simplified illustration of a system andmethodology for quality management constructed and operative inaccordance with a preferred embodiment of the present invention;

FIGS. 2A-2F together are a simplified illustration of a system andmethodology for quality management constructed and operative inaccordance with another preferred embodiment of the present invention;

FIG. 3A is a simplified illustration of a quality indicator constructedand operative in accordance with a preferred embodiment of the presentinvention for indicating elapsed time in temperature history;

FIG. 3B is a simplified illustration of a quality indicator constructedand operative in accordance with another preferred embodiment of thepresent invention for indicating elapsed time in temperature historywith delayed activation;

FIG. 3C is a simplified illustration of a quality indicator constructedand operative in accordance with another preferred embodiment of thepresent invention for separately indicating elapsed time and temperaturehistory;

FIG. 3D is a simplified illustration of a quality indicator constructedand operative in accordance with another preferred embodiment of thepresent invention for indicating elapsed time and temperature historywith delayed activation;

FIGS. 4A-4E together are a simplified illustration of the structure andoperation of an example of the quality indicator of FIG. 3A, inaccordance with a preferred embodiment of the present invention;

FIGS. 5A-5F together are a simplified illustration of the structure andoperation of an example of the quality indicator of FIG. 3B, inaccordance with a preferred embodiment of the present invention;

FIGS. 6A-6F together are a simplified illustration of the structure andoperation of an example of the quality indicator of FIG. 3C, inaccordance with a preferred embodiment of the present invention;

FIGS. 7A-7G together are a simplified illustration of the structure andoperation of an example of the quality indicator of FIG. 3D, inaccordance with a preferred embodiment of the present invention;

FIGS. 8A-8F together are a simplified illustration of the structure andoperation of an example of a quality indicator, in accordance with apreferred embodiment of the present invention for indicating elapsedtime in temperature history;

FIGS. 9A-9G together are a simplified illustration of the structure andoperation of an example of a quality indicator, in accordance withanother preferred embodiment of the present invention for indicatingelapsed time in temperature history with delayed activation;

FIG. 10 is a more detailed simplified illustration of the structure ofan example of the quality indicator of FIGS. 8A-9G; and

FIG. 11 is a simplified illustration of the structure and operation of aquality management system constructed and operative in accordance with apreferred embodiment of the present invention in the context of asupermarket.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

Reference is now made to FIGS. 1A-1F which together are a simplifiedillustration of a system and methodology for quality managementconstructed and operative in accordance with a preferred embodiment ofthe present invention. As seen in FIGS. 1A-1F, there is shown a qualitymanagement system and methodology for products including a multiplicityof quality indicators, here shown in the form of changeable barcodeindicators, each operative to provide a machine-readable, preferablybarcode-reader-readable, indication of exceedance of at least onethreshold by at least one product quality affecting parameter, at leastone indicator reader operative to read the quality indicators and toprovide output indications and a product type responsive indicationinterpreter operative to receive the output indications and to providehuman sensible, product quality status outputs.

Preferably, as elaborated hereinbelow with reference to FIG. 11, inaddition to receiving the output indications provided by the indicatorreader the indication interpreter may also receive product-relatedparameters such as product type, for example “meat”, and productmanufacturing date. Additionally or alternatively, the indicationinterpreter may receive other parameters, for example informationrelating to the quality indicator, such as the range of parameterssensed by the quality indicator, when the quality indicator wasactuated, and whether the quality indicator includes a delayedactivation feature. Additionally or alternatively, the indicationinterpreter may also received parameters relating to the source of theoutput indications provided, for example, whether the output indicationswere provided by a hand held device during inspection, or by thecheckout scanner of a retail store.

The product-related parameters and the other parameters, such as thoserelating to the quality indicator may be provided by the qualityindicator itself or by an additional, separate indicator, such as abarcode-bearing indicator. As a further alternative, these parametersmay be provided by sensors, a priori information otherwise available tothe indication interpreter or by manual entry.

The indication interpreter preferably forms part of or is otherwiseconnected to a quality indication computer, which may be remote from theindicator reader and which preferably includes a decision tableproviding product quality status outputs based on the output indicationsprovided by the indicator reader and the additional parameters.

It is appreciated that the additional parameters may be provided viaanother part of the same barcode or by another barcode associated withthe same product. Alternatively, the additional parameters may beprovided by other methods, such as using RFID technology.

The term “barcode” is used herein to refer to a machine readable opticalcode. In the examples' in the specification, linear, or one-dimensionalbar codes are illustrated. It is appreciated that the invention may beapplicable to two dimensional bar codes as well.

The quality indicator may incorporate a product code such as an EAN(European Article Number) or a UPC code (Universal Product Code). Theexamples shown in the description which follows all illustrate the useof an EAN code. Alternatively, the quality indicator may incorporate a 2of 5 interleaved barcode or any other suitable barcode ormachine-readable methodology.

Preferably, the quality indicator is operative to provide amachine-readable indication of exceedance of at least one threshold byat least one product quality affecting parameter. In a preferredembodiment the quality indicator provides a variable barcode having afixed barcode portion and at least one selectably appearing barcodeportion, both the fixed barcode portion and the combination of the fixedbarcode portion and at least one selectably appearing barcode portionhaving barcode checksum integrity when read by a conventional barcodereader. Accordingly, it is appreciated that the selectably appearingbarcode portion includes at least two digits which are different fromthose in the fixed barcode portion. The checksum is not necessarilychanged. The checksum digit may be part of the fixed barcode portion orpart of the selectably appearing barcode portion.

It is appreciated that in order to maintain checksum integrity under anEAN/UPC checksum system a barcode can be changed into another barcode byreplacing at least two digits thereof, one of which may be the checksumdigit. Each pair of digits can be replaced by another pair of digitswhere MOD10 of the weighted sum of both pairs is the same. For example,two adjacent digits in an EAN barcode, A1 in an even position and A2 inan odd position, may be replaced by two digits B1 and B2 such thatMOD10(3XA1+A2)=MOD10(3XB1+B2). If, for example, the pair (A1, A2) is (4,3) then (B1, B2) may be (8, 1), because MOD10 of the weighted sum inboth cases is 5. In the embodiments illustrated in this application adigit is replaced by another digit only by printing additional barwidths. Accordingly, the possible replacements which can be made byadding bar widths are provided in Table I.

TABLE I Possible replacements according to location of digit Right handDigit in barcode Left hand encoding encoding before change Odd parityEven parity All characters 0 3, 6 none none 1 3, 7 none none 2 7, 8 nonenone 3 none 0, 1, 5 0, 1, 5 4 6, 7, 8 none none 5 3, 7, 8 none none 6none 0, 4, 9 0, 4, 9 7 none 1, 2, 4, 5, 9 1, 2, 4, 5, 9 8 none 2, 4, 52, 4, 5 9 6, 7 none none

It is appreciated that the odd parity or the even parity of a digit isdefined in accordance with the EAN (European Article Number) standard.

It is also appreciated that a digit can also be replaced with anotherdigit by deleting bar widths.

According to a preferred embodiment of the present invention, thequality indicator provides a variable barcode having a visiblepre-actuation state, a different visible post-actuation state and atleast one visible state indicating exceedance of a corresponding one ofat least one threshold. The various states are preferably allmachine-readable by a conventional barcode reader. However one or moreof the states may not be machine-readable by the conventional barcodereader and the fact that they cannot be read provides statusinformation. For example, various situations in which a product is notto be sold or used may be indicated as non-readable states of thequality indicator.

Turning now to FIGS. 1A-1F, the present invention is illustrated in thecontext of a typical application, here a meat processing plant. Abarcoded quality indicator 100 is attached to or otherwise incorporatedinto each package 101 of processed meat. A package bearing a barcodedquality indicator 100 is typically an individual package suitable forretail sale.

In accordance with a preferred embodiment of the present invention, thequality indicators 100 may be assembled and/or actuated at the samelocation or at a location adjacent that at which the quality indicators100 are associated with packages 101. A suitable indicator assembler isindicated by reference numeral 102. It is appreciated that indicatorassembler 102 may be associated with an automatic actuator. It isfurther appreciated that the actuator may be automatic and may actuatethe quality indicator after it has been produced by indicator assembler102.

As seen in FIG. 1A, additional barcoded quality indicators 103, whichare preferably different from the quality indicators 100, are attachedto or otherwise incorporated into cartons 104 containing packages 101 ofprocessed meat bearing quality indicators 100. Preferably, the qualityindicators 103 are assembled by an indicator assembler 105 which issimilar to the quality indicator assembler 102, but is placed at alocation which is different from the location of the quality indicatorassembler 102. Alternatively, the quality indicators 103 may beassembled by the quality indicator assembler 102.

Different types of indicators may be employed for different types ofpackages. For example, the quality indicator used on a carton containinga plurality of individual packages may be more or less accurate or havea greater or lesser dynamic range of indications than the qualityindicator used on an individual package. The dynamic range of anindicator may be a greater or lesser range of temperatures and/or oftimes. Additionally or alternatively, the quality indicator on a cartonmay include an indicator capable of indicating exceedance of additionalthresholds, not included in the quality indicators of individualpackages contained therein, or fewer thresholds than the qualityindicators of individual packages contained therein.

In the illustrated embodiment, the quality indicators include an EAN(European Article Number) barcode. The quality indicators 100 arepreferably constructed to be actuatable by pulling a pull strip 106forming part thereof, as indicated by reference numeral 107. In theillustrated embodiment, the quality indicators 100 preferably have avisible pre-actuation state I, a different visible post-actuation stateII and a visible state III indicating exceedance of a predeterminedtemperature, for example 21 degrees Celsius, for at least apredetermined cumulative amount of time, for example one hour, as seenat reference numeral 125 in FIG. 1C. The quality indicators 100preferably also have an additional visible state IV, indicating theelapse of a predetermined amount of time since manufacture or otheractuation of the quality indicator, for example one week, regardless ofthe temperature, as seen at reference numeral 134 in FIG. 1C, and anadditional visible state V, indicating the elapse of an additionalamount of time, for example another week, regardless of the temperature,as seen at reference numeral 138 in FIG. 1D. The quality indicators 100can have yet a further visible state VI, indicating the exceedance of apredetermined temperature for a short predetermined duration, forexample the exceedance of 40 degrees Celsius for at least thirtyminutes, as seen in FIG. 1E, and another visible state VII, indicatingthe elapse of one year since manufacture or other actuation of thequality indicator regardless of temperature, as seen in FIG. 1F.

The visible states are readable by a barcode reader. For example, inthis illustrated embodiment, the pre-actuation state I is read as7431348787736, the post-actuation state II is read as 7811348787736, thevisible state III is read as 7811348782236, the visible state IV is readas 7817548787736, the visible state V is read as 7817562787736, thevisible state VI is read as 7811348787750 and the visible state VII isread as 7817562927736. It is appreciated that additional states of thequality indicator not presented in the illustrated embodiment may beindicated by combinations of the states described above. For example,when the temperature of the quality indicator exceeds 40 degrees Celsiusfor at least one hour it also exceeds 25 degrees Celsius for at leastone hour, which causes the quality indicator to assume the visible stateIII. However, the temperature in this case also exceeds 40 degrees forat least 30 minutes, which causes the quality indicator to assume thevisible state VI. Therefore, this combined exceedance is indicated by avisible state which combines the visible state III and the visible stateVI, and is read by a barcode reader as 7811348782250. It is furtherappreciated that the various visible states may occur in any suitableorder and not necessarily in the order indicated by their numbering.

As further seen in FIG. 1A, the quality indicators 103 are preferablyconstructed to be actuatable by pulling pull strip 108 forming partthereof, as indicated by reference numeral 109. In the illustratedembodiment, the indicators 103 preferably have a visible pre-actuationstate VIII, readable by a barcode reader typically as 7431348787750. Theindicators 103 preferably have a visible post-actuation state IX whichis different from pre-actuation state VIII and is readable by a barcodereader typically as 7437548787750. The indicators 103 preferably alsohave an additional at least one visible state X as seen, for example, atreference numeral 110 in FIG. 1A and at reference numeral 119 in FIG.1B, indicating exceedance of a predetermined temperature, for example 12degrees Celsius, for at least a predetermined cumulative amount of time,for example five hours. This further visible state is readable by abarcode reader typically as 7437548782250.

Alternatively, any of the visible states VIII, IX and X of the qualityindicators 103 may be associated with barcodes which are the same asbarcodes associated with states of the quality indicators 100. If thesame barcode is associated with states of both types of indicators, thenthe identity of the quality indicator read by a barcode reader isprovided to the indication interpreter by another method, for example bya manual entry to the database.

It is appreciated that the predetermined temperatures and thepredetermined cumulative amounts of time may be selected as appropriatefor a given application.

It is appreciated that as long as the temperature of the packages 101does not exceed a predetermined temperature for at least a predeterminedtotal amount of time, for example 21 degrees Celsius for one hour, andone week has not elapsed since manufacture or other actuation of thequality indicators, indicators 100 remain in the visible state II.

As seen in FIG. 1A, as long as the temperature of the cartons 104 doesnot exceed a predetermined temperature for at least a predeterminedtotal amount of time, for example 12 degrees Celsius for five hours, thequality indicators 103 remain in the visible state IX.

As further seen in FIG. 1A, if during loading of truck A as indicated byreference numeral 110, the temperature on the outside of one or morecartons 104 is at least 30 degrees Celsius for a period of five and ahalf hours, which is more then the predetermined total amount of time offive hours, the corresponding indicators 103 assume the further visiblestate X. This further visible state X does not revert to the visiblestate IX notwithstanding that the temperature of the carton 104subsequently drops below the predetermined temperature. These cartons,when received by the customer, will be subject to inspection todetermine whether the temperature of the packages 101 inside the cartons104 exceeded predetermined time and temperature thresholds.

Accordingly, upon inspection, as upon delivery, the quality indicators103 attached to the cartons 104 which were exposed to a temperature ofat least 30 degrees Celsius for a period of five and a half hours may beread by an inspector using a conventional barcode reader 113. Thebarcode in its visible state X preferably provides information to thequality indication computer 115 which enables the indication interpreterforming part thereof to provide an immediate indication of a qualitystatus, such as a BAD indication 116. This BAD indication 116 indicatesthat at some time in the history of the quality indicator 103, thecarton 104 to which it was attached was at least at the predeterminedtemperature for at least a predetermined total amount of time and thatthis event may have rendered one or more of the products in carton 104unacceptable for sale.

Should the quality indicator 103 be in the visible state VIII,indicating that proper actuation of the quality indicator 103 did notoccur, a NON-ACTUATED indication or a BAD indication 116 may be providedto an inspector or other interested party.

It is appreciated that until the cartons 104 are opened, which normallyoccurs only upon delivery, it is impractical to visually inspect theindicators 100 which are attached to the individual packages 101 insidethe cartons 104. Depending on the circumstances, the temperature of theindividual packages 101 within a carton 104 may or may not have exceeded21 degrees Celsius for one hour and the indicators 100 which areattached to the packages 101 may or may not be in the further visiblestate III. This normally can only be seen upon opening the cartons 104as shown in FIG. 1C.

It is a particular feature of the present invention that the time andtemperature thresholds of the quality indicators 100 and 103, placed onthe individual packages and the cartons containing them respectively,are preferably related in order to provide highly effective cold chainmanagement. It is preferable that indicators 103 provide a time intemperature warning even if, upon inspection, the indicators 100 showthat the individual packages 101 have not experienced unacceptabletemperatures. In order that an unacceptable rate of false alarms notoccur, the thresholds of the indicators 103 and 100 are preferablycalibrated with respect to each other based, inter alia, on empiricaldata.

As further seen in FIG. 1A, if during loading of truck B, the ambienttemperature on the outside of truck B reaches 25 degrees Celsius for onehour, which is less than the predetermined duration of five hours, thequality indicators 103 remain in visible state IX, as seen at referencenumeral 117.

At any stage, such as upon delivery, the quality indicators 103 can beread with a conventional barcode reader 113, which preferablycommunicates with a remote quality indication computer 115 and providesan immediate indication of a quality status, such as an OK indication118, to an inspector. It is appreciated that normally until delivery, itis impractical to visually inspect the indicators 100.

As stated above with relation to loading of truck A as indicated byreference numeral 110, it is preferable that the indicators 103 providea time in temperature threshold exceedance warning even if, uponinspection, the indicators 100 show that the individual packages 101have not experienced unacceptable temperatures for unacceptabledurations. Accordingly upon subsequent reading of the indicators 100 onthe packages 101 inside a carton 104 for which no such warning wasprovided, as indicated by reference numeral 123 in FIG. 1C, it is notexpected that the indicators 100 will indicate exceedance ofcorresponding time in temperature thresholds.

As seen in FIG. 1B, if during vehicle breakdown of truck B, the ambienttemperature outside of the cartons 104 is 15 degrees Celsius which ismore than the predetermined temperature of 12 degrees Celsius, for sixhours which is more than the predetermined total duration of five hours,the quality indicators 103 assume the further visible state X, as seenat reference numeral 119. This visible state X does not revert to thevisible state IX notwithstanding that the temperature of the cartons 104subsequently drops below the predetermined temperature.

Accordingly, upon inspection, as upon delivery, upon reading the qualityindicators 103 by an inspector using a conventional barcode reader 113,the barcode in its visible state X preferably provides information tothe quality indication computer 115 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a BAD indication 120. This BAD indication 120indicates that at some time in the history of the quality indicator 103,the carton 104 to which it was attached was at least at thepredetermined temperature for at least a predetermined total amount oftime and that this event may have rendered one or more of the productsin carton 104 unacceptable for sale. It is appreciated that normallyuntil cartons 104 are opened, typically following delivery, it isimpractical to visually inspect indicators 100.

Depending on the circumstances, the temperatures of the individualpackages 101 within the cartons 104 may or may not have exceeded 21degrees Celsius for one hour and the quality indicators 100 which areattached to the packages 101 may or may not be in the further visiblestate III. This normally can only be seen upon opening cartons 104 asshown in FIG. 1C.

As further seen from FIG. 1B and indicated by reference numeral 121,upon inspection, as upon delivery, the quality indicators 103 attachedto the cartons 104 which were delivered by truck A may be read by aninspector using a conventional barcode reader 113. As indicated byreference numeral 110 in FIG. 1A with relation to loading of truck A,one or more cartons 104 were exposed to a temperature of at least 30degrees Celsius for a period of five and a half hours, and the qualityindicators 103 of these cartons assumed the visible state X, indicatingexceedance of time in temperature thresholds.

In contrast, as indicated by reference numeral 121, the qualityindicators 103 of other cartons 104 which were not exposed to atemperature of at least 30 degrees Celsius for a period of five and ahalf hours remained in the visible state IX. The barcode in its visiblestate IX preferably provides information to the quality indicationcomputer 115 which enables the indication interpreter forming partthereof to provide an immediate OK indication 122.

Should the quality indicator 103 be in the visible state VIII,indicating that proper actuation of the quality indicator 103 did notoccur, a NON-ACTUATED indication or a BAD indication 120 may be providedto an inspector or other interested party.

Turning now specifically to FIG. 1C, it is seen that upon opening thecartons 104 of packages 101 which were delivered by truck B, asindicated by reference numeral 123, the quality indicators 100 attachedto the packages 101 are read by a conventional barcode reader 113. Inthis example, the quality indicators 100 of some of packages 101 are inthe visible state II, indicating that notwithstanding that an indicator103 on a carton 104 indicates exceedance of a time in temperaturethreshold, some of the packages, particularly those at the interior ofthe carton, may not have exceeded a corresponding time in temperaturethreshold and may be acceptable for sale.

Barcode reader 113 preferably communicates with a remote qualityindication computer 115 and provides an immediate OK indication 124 toan inspector, indicating that the temperature of some of packages 101did not exceed a predetermined temperature for at least a predeterminedtotal amount of time, for example 21 degrees Celsius for one hour.

This OK indication is in contrast to the BAD indication 120 provided bythe quality indicators 103 associated with the cartons 104 containingthese packages 101 as the result of refrigeration breakdown of truck B,as indicated by reference numeral 119 in FIG. 1B. As stated above withrelation to truck A loading indicated by reference numeral 110, it ispreferable that the indicators 103 provide a time in temperature warningeven if, upon inspection, the indicators 100 show that the individualpackages 101 have not experienced unacceptable temperatures.

It is further stated above that in order that an unacceptable rate offalse alarms not occur, the thresholds of indicators 103 and 100 arepreferably calibrated with respect to each other based, inter alia, onempirical data, and not necessarily as indicated in the example of FIGS.1A-1F, which is provided for illustration purposes. For example, a BADindication for a carton 104 containing packages 101 all having an OKindication can be prevented if indicators 103 attached to the cartons104 are calibrated to indicate the exceedance of a higher time ortemperature threshold than that of indicators 100 on packages 101.

As further seen in FIG. 1C and indicated by reference numeral 125, uponopening the cartons 104 of packages 101 which were delivered by truck Aand for which a BAD indication has already been provided by the qualityindicators 103 associated therewith during loading of truck A, asindicated by reference numeral 110 in FIG. 1A, it is seen that theindicators 100 assumed during transport a further visible state III. Itis appreciated that once the state III is reached, the quality indicator100 preferably does not thereafter revert to the state IInotwithstanding that the temperature of the package 101 subsequentlydrops below the predetermined temperature.

Accordingly, upon inspection, as upon delivery, upon reading the qualityindicator 100 by an inspector using a conventional barcode reader 113,the barcode in its visible state III preferably provides information tothe quality indication computer 115 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a BAD indication 127. This BAD indication 127indicates that at some time in the history of the quality indicator 100,the package 101 to which it was attached was at a temperature exceedingthe predetermined temperature for more than at least a predeterminedcumulative amount of time, and that this event has rendered the productin package 101 unacceptable for sale.

Should the quality indicator 100 be in the visible state I, indicatingthat proper actuation of the quality indicator 100 did not occur, aNON-ACTUATED indication or a BAD indication 127 may be provided to aninspector or other interested party.

It is appreciated, as discussed in more detail with reference to FIG. 11below, that whereas machine reading of the quality indicators 100 and103 provides an indication of whether or not a given event has occurred,the indication of a quality status by the quality indication computer115 provides an indication of whether and to what extent that event hasaffected the quality of a given product with which the quality indicator100 or the quality indicator 103 are associated. It is appreciated thatthere may be a great variation in the effect of a given event dependingon the type of product. Thus, for example, exposure to 21 degreesCelsius for a short period of time may cause fresh meat to be renderedunfit for sale but may not appreciably affect the quality or saleabilityof oranges.

As further seen in FIG. 1C, a user employing an imager-equippedtelephone or other suitable mobile communicator 128 may image thequality indicator 100 and communicate the image information to asuitably programmed quality indication computer 130, which may beidentical to the computer 115, and which is capable of reading thebarcode from the image information and providing to the user, via SMS orany other suitable communication methodology, an immediate indication ofa quality status, such as a GOOD QUALITY indication 132. This qualitystatus indicates that the product is safe for use. Alternatively, if theuser employs a barcode reader-equipped communicator, the communicatorcan provide to the computer 115 an output resulting from reading thebarcode.

It is appreciated that quality indication computer 130 may providereports to various interested entities, such as the manufacturer ordistributor of the products, health authorities and other governmentalor private entities, to enable real-time monitoring of the quality ofproducts offered for sale. The quality indication computer 130 may havecaller ID functionality so as to be able to identify the caller,classify the caller, for example as a customer, a manufacturer's QAinspector and a health inspector, and provide an appropriate qualityindication output. Additionally or alternatively, the quality indicationcomputer 130 may send messages to supermarket management regardingremedial steps to be taken, such as refrigeration maintenance or repairinstructions.

Turning now specifically to FIGS. 1C and 1D, it is seen that indicator100 may additionally and independently serve to indicate elapsed time.Thus, upon exceedance of the predetermined time period, for example oneweek, following manufacture or other actuation of the quality indicator100, the quality indicator 100 assumes yet a further visible state IV,as seen at reference numeral 134 in FIG. 1C. Upon elapse of a furtherpredetermined amount of time, typically a second week, the qualityindicator 100 may assume a still further visible state V, as seen atreference numeral 138 in FIG. 1D.

Accordingly, upon inspection, as indicated by reference numeral 134, asupon periodic stock inspection at a retail site, upon reading thequality indicator 100 by an inspector using a conventional barcodereader 113, the barcode in its visible state IV provides information tothe quality indication computer 115 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a SELL SOON indication 136. This SELL SOONindication 136 indicates that, since the predetermined time interval haselapsed, the package 101 to which it was attached should be positionedand/or priced for immediate sale.

It is seen in FIG. 1D that upon further inspection, as indicated byreference numeral 138, as upon periodic stock inspection at the retailsite, upon reading the quality indicator 100 by an inspector using aconventional barcode reader 113, the barcode in its visible state Vprovides information to the quality indication computer 115 whichenables the indication interpreter forming part thereof to provide animmediate indication of a quality status, such as an EXPIRED indication140. This EXPIRED indication 140 indicates that the package 101 to whichit was attached should be discarded, since the further predeterminedtime period has elapsed.

Additionally or alternatively, the further inspection may take placeautomatically at the checkout, where the quality indicator 100 is readby a checkout scanner 148. In such a case, the barcode in its visiblestate V provides information to the quality indication computer 115which enables the indication interpreter forming part thereof to providean immediate indication of a quality status, such as a DO NOT SELLindication 150, to the checkout clerk. This DO NOT SELL indication 150indicates that the package 101 to which it was attached may not be soldsince the further predetermined time period has elapsed. It isappreciated that the DO NOT SELL indication functionality describedabove provides a high level of control in implementing package-specificshelf-life restrictions and thus, by eliminating uncertainty regardingthe shelf life of a given product, may enable packaged products whichhave been maintained under optimal conditions to have longer shelf livesthan would otherwise be possible.

Additionally or alternatively, a further inspection prior to thecheckout may also be carried out by a customer at a suitable qualitycheck location within the store.

Turning now to FIG. 1E, it is seen that the indicator 100 mayadditionally and independently serve to indicate exceedance of apredetermined temperature for a relatively short time duration followingpurchase. Thus, if the package 101 bearing indicator 100 is left insidea vehicle in the sun and is exposed to 40 degrees Celsius for a durationas short as thirty minutes, the quality indicator 100 may assume afurther visible state VI. In such a situation, a purchaser, employing animager-equipped telephone or other suitable mobile communicator 153 mayimage the quality indicator 100 and communicate the image information toa suitably programmed quality indication computer 156, which may beidentical to computer 130 in FIG. 1C, and which is capable of readingthe barcode from the image information and providing to the user, viaSMS or any other suitable communication methodology, an immediateindication of a quality status, such as a DO NOT EAT indication 158.This quality status indicates that the product is not safe for humanconsumption. Alternatively, if the user employs a barcodereader-equipped communicator, the communicator can provide to thecomputer 156 an output resulting from reading the barcode.

Turning now to FIG. 1F, it is seen that indicator 100 may additionallyand independently serve to indicate elapsed time following purchase.Thus, upon exceedance of a predetermined long time period, such as 12months following manufacture or other actuation of the quality indicator100, the quality indicator 100 assumes a further visible state VII,which indicates that a predetermined amount of time has elapsed. Such asituation might occur when package 101 bearing indicator 100 isforgotten in a consumer's home freezer. In such a situation, theconsumer, employing imager-equipped telephone or other suitable mobilecommunicator 160 may image the quality indicator 100 and communicate theimage information to a suitably programmed quality indication computer166, which may be identical to the computer 130 in FIG. 1C, and which iscapable of reading the barcode from the image information and providingto the user, via SMS or any other suitable communication methodology, animmediate indication of a quality status, such as a DO NOT EATindication 168. This quality status indicates that the product is notsafe for human consumption. Alternatively, if the user employs a barcodereader-equipped communicator, the communicator can provide to thecomputer 166 an output resulting from reading the barcode.

Turning now to FIGS. 2A-2F, the present invention is illustrated in thecontext of a typical application, here a meat processing plant. Incontrast to the embodiment described hereinabove with reference to FIGS.1A-1F, in the illustrated example of FIGS. 2A-2F, where hot packagingand labeling takes place, it is necessary for activation of the qualityindicator to take place only once the product has been cooled to itsdesired long term storage temperature. A barcoded quality indicator 200is attached to or otherwise incorporated into each package 201 ofprocessed meat. A package bearing the barcoded quality indicator 200 istypically an individual package suitable for retail sale.

In accordance with a preferred embodiment of the present invention, thequality indicators 200 may be assembled and/or actuated at the samelocation or at a location adjacent that at which the quality indicators200 are associated with the packages 201. A suitable indicator assembleris indicated by reference numeral 202. It is appreciated that theindicator assembler 202 may be associated with an automatic actuator. Itis further appreciated that the actuator may be automatic and mayactuate the quality indicator after it has been produced by theindicator assembler 202.

As seen in FIG. 2A, additional barcoded quality indicators 203, whichare preferably different from the quality indicators 200, are attachedto or otherwise incorporated into cartons 204 containing packages 201 ofprocessed meat bearing quality indicators 200. Preferably, the qualityindicators 203 are assembled by an indicator assembler 205 which issimilar to the indicator assembler 202, but is placed at a locationwhich is different from the location of the indicator assembler 202.Alternatively, the quality indicators 203 may be assembled by theindicator assembler 202.

Different types of quality indicators may be employed for differenttypes of packages. For example, the quality indicator used on a cartoncontaining a plurality of individual packages may be more or lessaccurate or have a greater or lesser dynamic range of indications thanthe quality indicator used on an individual package. The dynamic rangeof a quality indicator may be a greater or lesser range of temperaturesand/or of times. Additionally or alternatively, the quality indicator ona carton may include a quality indicator capable of indicatingexceedance of additional thresholds, not included on the qualityindicators of individual packages contained therein, or fewer thresholdsthan the quality indicators of individual packages contained therein.

In the illustrated embodiment, the quality indicators include an EAN(European Article Number) barcode. The quality indicators 200 arepreferably constructed to be actuatable by pulling a pull strip 206forming part thereof, as indicated by reference numeral 207. In theillustrated embodiment, the quality indicators 200 preferably have avisible pre-actuation state I, a different visible post-actuation stateII and a visible state III indicating exceedance of a predeterminedtemperature, for example 21 degrees Celsius, for at least apredetermined total amount of time, for example one hour, as seen atreference numeral 225 in FIG. 2C. The quality indicators 200 preferablyalso have an additional visible state IV, indicating the elapse of apredetermined amount of time since manufacture or other actuation of thequality indicator, for example one week, regardless of the temperature,as seen at reference numeral 234 in FIG. 2C, and an additional visiblestate V, indicating the elapse of an additional amount of time, forexample another week, regardless of the temperature, as seen atreference numeral 238 in FIG. 2D. The quality indicators 200 can haveyet a further visible state VI, indicating the exceedance of apredetermined temperature for a short predetermined duration, forexample the exceedance of 40 degrees Celsius for at least thirtyminutes, as seen in FIG. 2E, and another visible state VII, indicatingthe elapse of one year since manufacture or other actuation of thequality indicator regardless of temperature, as seen in FIG. 2F.

The visible states are readable by a barcode reader. For example, inthis illustrated embodiment, the pre-actuation state I is read as7431348787736, the post-actuation state II is read as 7811348787736, thevisible state III is read as 7811348782236, the visible state IV is readas 7817548787736, the visible state V is read as 7817562787736, thevisible state VI is read as 78113487877 50 and the visible state VII isread as 7817562927736. It is appreciated that additional states of thequality indicator not presented in the illustrated embodiment may beindicated by combinations of the states described above. For example,when the temperature of the quality indicator exceeds 40 degrees Celsiusfor at least one hour it also exceeds 25 degrees Celsius for at leastone hour, which causes the quality indicator to assume visible stateIII. However, the temperature in this case also exceeds 40 degrees forat least 30 minutes, which causes the quality indicator to assume thevisible state VI. Therefore, this combined exceedance is indicated by avisible state which combines the visible state III and the visible stateVI, and is read by a barcode reader as 7811348782250. It is furtherappreciated that the various visible states may occur in any suitableorder and not necessarily in the order indicated by their numbering.

As further seen in FIG. 2A, the quality indicators 203 are preferablyconstructed to be actuatable by pulling pull strip 208 forming partthereof, as indicated by reference numeral 209. In the illustratedembodiment, the indicators 203 preferably have a visible pre-actuationstate VIII, readable by a barcode reader typically as 7431348787750.Indicators 203 preferably have a visible post-actuation state IX whichis different from pre-actuation state VIII and is readable by a barcodereader typically as 7437548787750. Indicators 203 preferably also havean additional at least one visible state X as seen, for example, atreference numeral 210 in FIG. 2A and at reference numeral 219 in FIG.2B, indicating exceedance of a predetermined temperature, for example 12degrees Celsius, for at least a predetermined cumulative amount of time,for example five hours. This further visible state is readable by abarcode reader typically as 7437548782250.

Alternatively, any of the visible states VIII, IX and X of the qualityindicators 203 may be associated with barcodes which are the same asbarcodes associated with states of the quality indicators 200. If thesame barcode is associated with states of both types of indicators, thenthe identity of the quality indicator read by a barcode reader isprovided to the indication interpreter by another method, for example bya manual entry to the database.

It is appreciated that the predetermined temperatures and thepredetermined cumulative amounts of time may be selected as appropriatefor a given application.

In contrast to the embodiment described hereinabove with reference toFIGS. 1A-1F, actuation, as by pulling the pull strip 206 or the pullstrip 208, does not result in immediate activation of the indicationfunctionality of the respective quality indicators 200 and 203. Thus thequality indicators 200 and 203 do not provide a machine readableindication of exceedance of thresholds which takes place during a periodof time between actuation and activation. Typically the resultingactivation delay may be 8 hours following actuation. It is seen in FIG.2A that during the activation delay the quality indicators 200 and 203are not sensitive to temperature and retain their respective visiblepost-actuation states II and IX.

It is appreciated that various types of indicators may be employedtogether in a quality management system. In some indicators actuationmay result in the immediate activation of the quality indicator, and inother indicators activation of the quality indicator following actuationmay be delayed.

It is appreciated that following elapse of the activation delay, as longas the temperature of the packages 201 does not exceed a predeterminedtemperature for at least a predetermined total amount of time, forexample 21 degrees Celsius for one hour, and one week has not elapsedsince manufacture or other activation of the quality indicator, theindicators 200 remain in the visible state II.

As seen in FIG. 2A as long as, following elapse of the activation delay,the temperature of the carton 204 of packages 201 does not exceed apredetermined temperature for at least a predetermined cumulative amountof time, for example 12 degrees Celsius for five hours, the qualityindicators 203 remain in the visible state IX.

As further seen in FIG. 2A, if during loading of truck A as indicated byreference numeral 210, after the elapse of the activation delay thetemperature on the outside of one or more cartons 204 is at least 30degrees Celsius for a period of five and a half hours, which is morethen the predetermined total amount of time of five hours, thecorresponding indicators 203 assume the further visible state X. Thisfurther visible state X does not revert to the visible state IXnotwithstanding that the temperature of the carton 204 subsequentlydrops below the predetermined temperature. These cartons, when receivedby the customer, will be subject to inspection to determine whether thetemperature of the packages 201 inside the cartons 204 exceededpredetermined time in temperature thresholds.

Accordingly, upon inspection, as upon delivery, the quality indicators203 attached to the cartons 204 which were exposed to a temperature ofat least 30 degrees Celsius for a period of five and a half hours may beread by an inspector using a conventional barcode reader 213. Thebarcode in its visible state X preferably provides information to thequality indication computer 215 which enables the indication interpreterforming part thereof to provide an immediate indication of a qualitystatus, such as a BAD indication 216. This BAD indication 216 indicatesthat at some time in the history of the quality indicator 203, thecarton 204 to which it was attached was at least at the predeterminedtemperature for at least a predetermined total amount of time and thatthis event may have rendered one or more of the products in carton 204unacceptable for sale.

Should the quality indicator 203 be in the visible state VIII,indicating that proper actuation of the quality indicator 203 did notoccur, a NON-ACTUATED indication or a BAD indication 216 may be providedto an inspector or other interested party.

It is appreciated that until the cartons 204 are opened, which normallyoccurs only upon delivery, it is impractical to visually inspect theindicators 200 which are attached to the individual packages 201 insidethe cartons 204. Depending on the circumstances, the temperature of theindividual packages 201 within a carton 204 may or may not have exceeded21 degrees Celsius for one hour and the quality indicators 200 which areattached to the packages 201 may or may not be in the further visiblestate III. This normally can only be seen upon opening the cartons 204as shown in FIG. 2C.

It is a particular feature of the present invention that the time andtemperature thresholds of the quality indicators 200 and 203, placed onthe individual packages and the cartons containing them respectively,are preferably related in order to provide highly effective cold chainmanagement. It is preferable that the quality indicators 203 provide atime in temperature warning even if, upon inspection, indicators 200show that the individual packages 201 have not experienced unacceptabletemperatures. In order that an unacceptable rate of false alarms notoccur, the thresholds of indicators 203 and 200 are preferablycalibrated with respect to each other based, inter alia, on empiricaldata.

As further seen in FIG. 2A, if during loading of truck B, after theelapse of the activation delay the ambient temperature on the outside oftruck B reaches 25 degrees Celsius for one hour, which is less than thepredetermined duration of five hours, the quality indicator 203 remainsin the visible state IX, as seen at reference numeral 217.

At any stage, such as upon delivery, the quality indicator 203 can beread with a conventional barcode reader 213, which preferablycommunicates with a remote quality indication computer 215 and providesan immediate indication of a quality status, such as an OK indication218, to an inspector. It is appreciated that normally until delivery, itis impractical to visually inspect indicators 200.

As stated above with relation to loading of truck A as indicated byreference numeral 210, it is preferable that the quality indicators 203provide a time in temperature threshold exceedance warning even if, uponinspection, the quality indicators 200 show that the individual packages201 have not experienced unacceptable temperatures for unacceptabledurations. Accordingly upon subsequent reading of the quality indicators200 on packages 201 inside a carton 204 for which no such warning wasprovided, as indicated by reference numeral 223 in FIG. 2C, it is notexpected that indicators 200 will indicate exceedance of correspondingtime in temperature thresholds.

As seen in FIG. 2B, if during vehicle breakdown of truck B, after theelapse of the activation delay the ambient temperature outside of thecartons 204 is 15 degrees Celsius which is more than the predeterminedtemperature of 12 degrees Celsius, for six hours which is more than thepredetermined total duration of five hours, the quality indicatorassumes the further visible state X, as seen at reference numeral 219.This visible state X does not revert to the visible state IXnotwithstanding that the temperature of the cartons 204 subsequentlydrops below the predetermined temperature.

Accordingly, upon inspection, as upon delivery, upon reading the qualityindicator 203 by an inspector using a conventional barcode reader 213,the barcode in its visible state X preferably provides information tothe quality indication computer 215 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a BAD indication 220. This BAD indication 220indicates that at some time in the history of the quality indicator 203,the carton 204 to which it was attached was at least at thepredetermined temperature for at least a predetermined total amount oftime and that this event may have rendered one or more of the productsin carton 204 unacceptable for sale. It is appreciated that normallyuntil cartons 204 are opened, typically following delivery, it isimpractical to visually inspect indicators 200.

Depending on the circumstances, the temperatures of the individualpackages 201 within the cartons 204 may or may not have exceeded 21degrees Celsius for one hour and the quality indicators 200 which areattached to the packages 201 may or may not be in the further visiblestate III. This normally can only be seen upon opening cartons 204 asshown in FIG. 2C.

As further seen from FIG. 2B and indicated by reference numeral 221,upon inspection, as upon delivery, the quality indicators 203 attachedto the cartons 204 which were delivered by truck A may be read by aninspector using a conventional barcode reader 213. As indicated byreference numeral 210 in FIG. 2A with relation to loading of truck A,one or more cartons 204 were exposed to a temperature of at least 30degrees Celsius for a period of five and a half hours, and the qualityindicators 203 of these cartons assumed the visible state X, indicatingexceedance of time in temperature thresholds.

In contrast, as indicated by reference numeral 221, the qualityindicators 203 of other cartons 204 which were not exposed to atemperature of at least 30 degrees Celsius for a period of five and ahalf hours remained in the visible state IX. The barcode in its visiblestate IX preferably provides information to the quality indicationcomputer 215 which enables the indication interpreter forming partthereof to provide an immediate OK indication 222.

Should the quality indicator 203 be in visible state VIII, indicatingthat proper actuation of the quality indicator 203 did not occur, aNON-ACTUATED indication or a BAD indication 220 may be provided to aninspector or other interested party.

Turning now specifically to FIG. 2C, it is seen that upon opening thecartons 204 of packages 201 which were delivered by truck B, asindicated by reference numeral 223, the quality indicators 200 attachedto the packages 201 are read by a conventional barcode reader 213. Inthis example, the quality indicators 200 of some of packages 201 are inthe visible state II, indicating that notwithstanding that an indicator203 on a carton 204 indicates exceedance of a time in temperaturethreshold, some of the packages, particularly those at the interior ofthe carton, may not have exceeded a corresponding time in temperaturethreshold and may be acceptable.

Barcode reader 213 preferably communicates with a remote qualityindication computer 215 and provides an immediate OK indication 224 toan inspector, indicating that the temperature of some of the packages201 did not exceed a predetermined temperature for at least apredetermined total amount of time, for example 21 degrees Celsius forone hour.

This OK indication is in contrast to the BAD indication 220 provided bythe quality indicators 203 associated with cartons 204 containing thesepackages 201 as the result of refrigeration breakdown of truck B, asindicated by reference numeral 219 in FIG. 2B. As stated above withrelation to truck A loading indicated by reference numeral 210, it ispreferable that indicators 203 provide a time in temperature warningeven if, upon inspection, indicators 200 show that the individualpackages 201 have not experienced unacceptable temperatures.

It is further stated above that in order that an unacceptable rate offalse alarms not occur, the thresholds of the quality indicators 203 and200 are preferably calibrated with respect to each other based, interalia, on empirical data, and not necessarily as indicated in the exampleof FIGS. 2A-2F, which is provided for illustration purposes. Forexample, a BAD indication for a carton 204 containing packages 201 allhaving an OK indication can be prevented if the quality indicators 203attached to the cartons 204 are calibrated to indicate the exceedance ofa higher time or temperature threshold than that of indicators 200 onpackages 201.

As further seen in FIG. 2C and indicated by reference numeral 225, uponopening the cartons 204 of packages 201 which were delivered by truck Aand for which a BAD indication has already been provided by the qualityindicators 203 associated therewith during loading of truck A, asindicated by reference numeral 210 in FIG. 2A, it is seen thatindicators 200 assumed during transport the further visible state III.It is appreciated that once the state III is reached, the qualityindicator 200 preferably does not thereafter revert to the state IInotwithstanding that the temperature of the package 201 subsequentlydrops below the predetermined temperature.

Accordingly, upon inspection, as upon delivery, upon reading the qualityindicator 200 by an inspector using a conventional barcode reader 213,the barcode in its visible state III preferably provides information tothe quality indication computer 215 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a BAD indication 227. This BAD indication 227indicates that at some time in the history of the quality indicator 200,the package 201 to which it was attached was at a temperature exceedingthe predetermined temperature for more than at least a predeterminedcumulative amount of time, and that this event has rendered the productin package 201 unacceptable for sale.

Should the quality indicator 200 be in the visible state I, indicatingthat proper actuation of the quality indicator 200 did not occur, aNON-ACTUATED indication or a BAD indication 227 may be provided to aninspector or other interested party.

It is appreciated, as discussed in more detail with reference to FIG. 11below, that whereas machine reading of the quality indicators 200 and203 provides an indication of whether or not a given event has occurred,the indication of a quality status by the quality indication computer215 provides an indication of whether and to what extent that event hasaffected the quality of a given product with which the quality indicator200 or the quality indicator 203 are associated. It is appreciated thatthere may be a great variation in the effect of a given event dependingon the type of product. Thus, for example, exposure to 21 degreesCelsius for a short period of time may cause fresh meat to be renderedunfit for sale but may not appreciably affect the quality or saleabilityof oranges.

As further seen in FIG. 2C, a user employing an imager-equippedtelephone or other suitable mobile communicator 228 may image thequality indicator 200 and communicate the image information to asuitably programmed quality indication computer 230, which may beidentical to the computer 215, and which is capable of reading thebarcode from the image information and providing to the user, via SMS orany other suitable communication methodology, an immediate indication ofa quality status, such as a GOOD QUALITY indication 232. This qualitystatus indicates that the product is safe for use. Alternatively, if theuser employs a barcode reader-equipped communicator, the communicatorcan provide to the computer 215 an output resulting from reading thebarcode.

It is appreciated that the quality indication computer 230 may providereports to various interested entities, such as the manufacturer ordistributor of the products, health authorities and other governmentalor private entities, to enable real-time monitoring of the quality ofproducts offered for sale. The quality indication computer 230 may havecaller ID functionality so as to be able to identify the caller,classify the caller, for example as a customer, a manufacturer's QAinspector and a health inspector, and provide an appropriate qualityindication output. Additionally or alternatively, the quality indicationcomputer 230 may send messages to supermarket management regardingremedial steps to be taken, such as refrigeration maintenance or repairinstructions.

Turning now specifically to FIGS. 2C and 2D, it is seen that theindicators 200 may additionally and independently serve to indicateelapsed time. Thus, upon exceedance of the predetermined time period,for example one week, following manufacture or other activation of thequality indicator 200, the quality indicator 200 assumes yet a furthervisible state IV, as seen at reference numeral 234 in FIG. 2C. Uponelapse of a further predetermined amount of time, typically a secondweek, the quality indicator 200 may assume the still further visiblestate V, as seen at reference numeral 238 in FIG. 2D.

Accordingly, upon inspection, as indicated by reference numeral 234, asupon periodic stock inspection at a retail site, upon reading thequality indicator 200 by an inspector using a conventional barcodereader 213, the barcode in its visible state IV provides information tothe quality indication computer 215 which enables the indicationinterpreter forming part thereof to provide an immediate indication of aquality status, such as a SELL SOON indication 236. This SELL SOONindication 236 indicates that, since the predetermined time interval haselapsed, the package 201 to which it was attached should be positionedand/or priced for immediate sale.

It is seen in FIG. 2D that upon further inspection, as indicated byreference numeral 238, as upon periodic stock inspection at the retailsite, upon reading the quality indicator 200 by an inspector using aconventional barcode reader 213, the barcode in its visible state Vprovides information to the quality indication computer 215 whichenables the indication interpreter forming part thereof to provide animmediate indication of a quality status, such as an EXPIRED indication240. This EXPIRED indication 240 indicates that the package 201 to whichit was attached should be discarded, since the further predeterminedtime period has elapsed.

Additionally or alternatively, the further inspection may take placeautomatically at the checkout, where the quality indicator 200 is readby a checkout scanner 248. In such a case, the barcode in its visiblestate V provides information to the quality indication computer 215which enables the indication interpreter forming part thereof to providean immediate indication of a quality status, such as a DO NOT SELLindication 250, to the checkout clerk. This DO NOT SELL indication 250indicates that the package 201 to which it was attached may not be soldsince the further predetermined time period has elapsed. It isappreciated that the DO NOT SELL indication functionality describedabove provides a high level of control in implementing package-specificshelf-life restrictions and thus, by eliminating uncertainty regardingthe shelf life of a given product, may enable packaged products whichhave been maintained under optimal conditions to have longer shelf livesthan would otherwise be possible.

Additionally or alternatively, a further inspection prior to thecheckout may also be carried out by a customer at a suitable qualitycheck location within the store.

Turning now to FIG. 2E, it is seen that the indicators 200 mayadditionally and independently serve to indicate exceedance of apredetermined temperature for a relatively short time duration followingpurchase. Thus, if the package 201 bearing indicator 200 is left insidea vehicle in the sun and is exposed to 40 degrees Celsius for a durationas short as thirty minutes, the quality indicator 200 may assume afurther visible state VI. In such a situation, a purchaser, employing animager-equipped telephone or other suitable mobile communicator 253 mayimage the quality indicator 200 and communicate the image information toa suitably programmed quality indication computer 256, which may beidentical to the computer 230 in FIG. 2C, and which is capable ofreading the barcode from the image information and providing to theuser, via SMS or any other suitable communication methodology, animmediate indication of a quality status, such as a DO NOT EATindication 258. This quality status indicates that the product is notsafe for human consumption. Alternatively, if the user employs a barcodereader-equipped communicator, the communicator can provide to thecomputer 256 an output resulting from reading the barcode.

Turning now to FIG. 2F, it is seen that indicator 200 may additionallyand independently serve to indicate elapsed time following purchase.Thus, upon exceedance of a predetermined long time period, such as 12months following manufacture or other activation of the qualityindicator 200, the quality indicator 200 assumes a further visible stateVII, which indicates that a predetermined amount of time has elapsed.Such a situation might occur, when package 201 bearing indicator 200 isforgotten in a consumer's home freezer. In such a situation, theconsumer, employing imager-equipped telephone or other suitable mobilecommunicator 260 may image the quality indicator 200 and communicate theimage information to suitably programmed quality indication computer266, which may be identical to the computer 230 in FIG. 2C, and which iscapable of reading the barcode from the image information and providingto the user, via SMS or any other suitable communication methodology, animmediate indication of a quality status, such as a DO NOT EATindication 268. This quality status indicates that the product is notsafe for human consumption. Alternatively, if the user employs a barcodereader-equipped communicator, the communicator can provide to thecomputer 266 an output resulting from reading the barcode.

Reference is now made to FIGS. 3A-3D, which are simplified illustrationsof quality indicators constructed and operative in accordance with apreferred embodiment of the present invention for indicating temperaturehistory, elapsed time and a combination of elapsed time and temperaturehistory.

FIG. 3A illustrates a package of meat 300 including a combinationelapsed time in temperature indicator 301 constructed and operative inaccordance with a preferred embodiment of the present invention of thetype described hereinabove with reference to FIGS. 1A-1F. The qualityindicator 301 is typically constructed to be actuatable by pulling apull strip 302 forming part thereof. As illustrated in FIG. 3A,indicator 301 includes a barcode which is in a visible state 303,typically readable by a barcode reader as 7431348787736, prior toactuation, as indicated by designator A.

Following actuation, indicator 301 presents a barcode which is in avisible state 304, typically readable by a barcode reader as7811348787736 including a changed portion 305 as long as the temperatureof the package 300 does not exceed a predetermined temperature for atleast a predetermined cumulative amount of time, for example 21 degreesCelsius for one hour, as indicated by designator B. Once the temperatureof the package 300 is more than the predetermined temperature for atleast a predetermined cumulative amount of time, such as 21 degreesCelsius for one hour, the quality indicator presents a barcode which isin a visible state 306, typically readable by a barcode reader as7811348782236, including a changed portion 308, as indicated bydesignator C. It is appreciated that once the state 306 is reached, thequality indicator preferably does not thereafter revert to the state 304notwithstanding that the temperature of the package 300 subsequentlydrops below the predetermined temperature.

FIG. 3B illustrates a package of salami 320 including a combinationelapsed time in temperature indicator 321 constructed and operative inaccordance with a preferred embodiment of the present invention, of thetype described hereinabove with reference to FIGS. 2A-2F. The qualityindicator 321 is typically constructed to be actuatable by pulling apull strip 322 forming part thereof.

As illustrated in FIG. 3B, indicator 321 includes a barcode which is ina first visible state 323, typically readable by a barcode reader as7431348787736, prior to actuation as indicated by designator A, and in asecond visible state 324, typically readable by a barcode reader as7811348787736 including a changed portion 325 following actuation, asindicated by designator B. The quality indicator 321 preferably remainsin the second visible state 324 prior to activation, for at least apredetermined time following actuation, typically 8 hours, irrespectiveof the temperature of the quality indicator 321 as indicated bydesignators B and C.

Upon activation, once the temperature of the package 320 is more than apredetermined temperature for at least a predetermined total duration,such as 21 degrees Celsius for one hour, as indicated by designator D,the quality indicator presents a barcode which is in a visible state326, typically readable by a barcode reader as 7811348782236, includinga changed portion 328. It is appreciated that once the state 326 isreached, the quality indicator preferably does not thereafter revert tothe state 324 notwithstanding that the temperature of the package 320subsequently drops below the predetermined temperature.

FIG. 3C illustrates a package of meat 340 including an indicator forseparately indicating elapsed time and temperature 341, constructed andoperative in accordance with a preferred embodiment of the presentinvention, of the type described hereinabove with reference to FIGS.1A-1F. The quality indicator 341 is typically constructed to beactuatable by pulling a pull strip 342 forming part thereof.

As illustrated in FIG. 3C, indicator 341 includes a barcode which is ina visible state 343, typically readable by a barcode reader as7431348787736, prior to actuation, as indicated by designator A.Following actuation, indicator 341 presents a barcode which is in avisible state 344, typically readable by a barcode reader as7811348787736 including a changed portion 345 as long as the temperatureof the package 340 does not exceed a predetermined temperature for atleast a predetermined cumulative amount of time, such as for example atemperature of 21 degrees Celsius for at least one hour, and when nomore than a predetermined time period, typically seven days, has elapsedsince actuation of the quality indicator, as indicated by designator B.

Once the temperature has exceeded 21 degrees Celsius for one hour, butthe predetermined time period has not elapsed since actuation, thequality indicator presents a barcode which is in a visible state 346,typically readable by a barcode reader as 7811348782236, including achanged portion 347, as indicated by designator C. It is appreciatedthat once the state 346 is reached, the quality indicator preferablydoes not thereafter revert to the state 344 notwithstanding that thetemperature of the package 340 subsequently drops below thepredetermined temperature.

Once the predetermined time has elapsed since actuation of indicator341, the quality indicator presents a further visible state 348,typically readable by a barcode reader as 7817548782236 including achanged portion 349, as indicated by designator D. Once an additionalamount of time has elapsed, for example another week, the qualityindicator presents a further visible state 350, typically readable by abarcode reader as 7817562782236, including a changed portion 351 asindicated by designator E.

FIG. 3D illustrates a package of meat 360 including an indicator forseparately indicating elapsed time and temperature 361, constructed andoperative in accordance with a preferred embodiment of the presentinvention, of the type described hereinabove with reference to FIGS.2A-2F. The quality indicator 361 is typically constructed to beactuatable by pulling a pull strip 362 forming part thereof.

As illustrated in FIG. 3D, indicator 361 includes a barcode which is ina first visible state 363, typically readable by a barcode reader as7431348787736, prior to actuation as indicated by designator A and in asecond visible state 364, typically readable by a barcode reader as7811348787736, including a changed portion 365 following actuation asindicated by designator B. The quality indicator 361 preferably remainsat the second visible state 364 for at least a predetermined time,typically 8 hours, prior to activation, irrespective of the temperatureand elapsed time of the quality indicator 361 as indicated bydesignators B and C.

Following activation, once the temperature has exceeded a predeterminedtemperature for at least a predetermined cumulative amount of time, forexample 21 degrees Celsius for one hour, but the predetermined timeperiod, typically seven days, has not elapsed since activation, thequality indicator presents a barcode which is in visible state 366,typically readable by a barcode reader as 7811348782236, including achanged portion 367, as indicated by designator D. It is appreciatedthat once the state 366 is reached, the quality indicator preferablydoes not thereafter revert to the state 364 notwithstanding that thetemperature of the package 360 subsequently drops below thepredetermined temperature. Once the predetermined time has elapsed sinceactivation of indicator 361 the quality indicator presents a furthervisible state 368, typically readable by a barcode reader as7817548782236, including a changed portion 369, as indicated bydesignator E. Once an additional amount of time has elapsed, for exampleanother week, the quality indicator presents a further visible state370, typically readable by a barcode reader as 7817562782236, includinga changed portion 371 as indicated by designator F.

Reference is now made to FIGS. 4A-7G, which, respectively, aresimplified illustrations of the structure and operation of examples ofthe quality indicators of FIGS. 3A-3D constructed and operative inaccordance with a preferred embodiment of the present invention forindicating temperature history, elapsed time and a combination oftemperature history and elapsed time.

Reference is now made to FIGS. 4A-4E, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator 301 of FIG. 3A for indicating time in temperaturehistory. As seen in FIG. 4A, the quality indicator, here designated byreference numeral 400, preferably includes a barcode defining layer 402,which is preferably printed on a transparent substrate. The printing onthe transparent substrate preferably defines a background area, which ispreferably printed in a white color, a barcode in a first visible state404 which is preferably printed in a black color, and a plurality oftransparent areas 406 and 407 associated with the barcode, which are notprinted. Alternatively, the background area and the barcode are printedin such colors as to define high contrast therebetween. The barcode inthe first visible state 404 is machine readable in this embodiment andis typically readable by a barcode reader as 7431348787736.

If transparent areas 406 are colored and read together with the barcodein the first visible state 404, there is provided a barcode in a secondvisible state 408 typically readable by a barcode reader as7811348787736. If both transparent areas 406 and 407 are colored andread together with the barcode in the first visible state 404, there isprovided a barcode in a third visible state 409 typically readable by abarcode reader as 7811348782236. There is also a theoretical possibilitythat the transparent areas 407 could be colored and 406 could not becolored, but it is not practical in the present embodiment.

Disposed behind the transparent areas 407 extending perpendicular to thebarcode and preferably adhered to the barcode defining layer 402 is acolorable element 410, such as Whatman No. 3 filter paper commerciallyavailable from Whatman International [CAT#: 1003917], which untilcolored is normally white. Disposed behind the barcode defining layer402 and behind the colorable element 410 is a pull strip 411,corresponding to the pull strip 106 in FIG. 1A, and the pull strip 302in FIG. 3A. The pull strip 411 is preferably white and prevents thepassage therethrough of coloring agents employed in this embodiment ofthe invention. Preferably, the pull strip 411 is formed of polyester,for example Melinex® 401, commercially available from DuPont ofWilmington, Del., and is preferably 75 micrometers thick.

Disposed behind the pull strip 411 is a back layer 412 to which ispreferably adhered, rearwardly of colorable element 410 but notrearwardly of the barcode, a temperature responsive coloring element413, such as a pad, for example, K-R; 210/34/28, commercially availablefrom Noam-Urim of Kibbutz Urim, Israel, impregnated with a coloringagent, such as Sudan Black, a black color dye [CAS: 4197-25-5],dissolved at a ratio of 1 gram per 1 kg in a solution of 74.25% Coconutoil [CAS: 8001-31-8], 24.75% Oleic acid [CAS: 112-80-1] and 1% Hexanoicacid [CAS: 142-62-1].

A colored area 415 is formed on the back layer 412, rearwardly of thetransparent areas 406, in order to define high contrast with the barcodedefining layer 402, when the pull strip 411 is removed.

Until such time as the pull strip 411 is removed, the quality indicator400 is nonresponsive to temperature changes and remains in the firstvisible state 404.

Turning to FIG. 4B, once the pull strip 411 is removed, the qualityindicator 400 becomes responsive to temperature changes. As long as thetemperature at the quality indicator does not exceed a predeterminedtemperature, for example 21 degrees Celsius, for at least apredetermined cumulative amount of time, typically one hour, theportions of the colored area 415 which are visible through thetransparent areas 406 appear similar to the bars of the barcode in thefirst visible state 404 and can be read together therewith as a singlebarcode in the second visible state 408.

Turning to FIG. 4C, when the pull strip 411 has been removed and whenthe temperature at the quality indicator exceeds 21 degrees Celsius, thecoloring agent in the coloring element 413 begins to melt and bereleased from the coloring element 413 and begins to diffuse through thecolorable element 410.

It is appreciated that if the temperature thereafter drops below 21degrees Celsius the coloring agent continues to diffuse through thecolorable element 410. If, after the temperature reaches 21 degreesCelsius, the temperature drops below 17 degrees Celsius, the coloringagent becomes solid and diffusion thereof through the colorable element410 is suspended until the temperature again reaches 21 degrees Celsius.

It is appreciated that the elapsed time from the start of diffusion ofthe coloring agent from the coloring element 413 along the colorableelement 410 until portions of the colorable element 410 which arevisible through the transparent areas 407 start to become colored isdefined for example by the length of the colorable element 410 betweenthe area in front of coloring element 413 and the area underlying thetransparent areas 407. Additionally, this elapsed time is a function ofthe material from which the colorable element 410 is made.

As seen in FIG. 4D, when the temperature is at least 21 degrees Celsiusfor at least a predetermined cumulative amount of time, such as 21degrees Celsius for fifty minutes, the coloring agent diffuses throughthe colorable element 410, such that the portions of the colorableelement 410 which are visible through the transparent areas 407 start tobecome colored and appear similar to the bars of the barcode in thefirst visible state 404. It is appreciated that since the direction ofdiffusion of the coloring agent through the colorable element 410underlying the barcode is perpendicular to the barcode, as indicated byreference numeral 417, portions of the barcode in the transparent areas407 can be read together with the barcode in the first visible state 404and with the transparent areas 406 as a single barcode even before thecolorable element 410 is fully colored by the coloring agent.

The portions of the barcode in the transparent areas 407 which arecolored and appear similar to the bars of the barcode in the firstvisible state 404 can be read together therewith and with thetransparent areas 406 as a single barcode in the third visible state409. The portions of the barcode in the transparent areas 407 which arenot colored and do not appear similar to the bars of the barcode in thefirst visible state 404 can be read together with the transparent areas406 as a single barcode in the second visible state 408. Thus it isappreciated that normally at all times following actuation, a readablebarcode is present.

It is appreciated that the appearance of the quality indicator 400during the transition illustrated in FIG. 4D may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 400 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 4E, following the elapse of an additional amount oftime at a temperature of at least 21 degrees Celsius, typically 10minutes, the coloring agent is fully diffused through colorable element410. Consequently, all portions of the colorable element 410 which arevisible through the transparent areas 407 are colored and appear similarto the bars of the barcode in the first visible state 404, and can beread together therewith and with the transparent areas 406 as a singlebarcode in the third visible state 409.

Reference is now made to FIGS. 5A-5F, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator 321 of FIG. 3B for indicating time in temperaturehistory. As seen in FIG. 5A, the quality indicator, here designated byreference numeral 500, preferably includes a barcode defining layer 502,which is preferably printed on a transparent substrate. The printing onthe transparent substrate preferably defines a background area, which ispreferably printed in a white color, a barcode in a first visible state504 which is preferably printed in a black color, and a plurality oftransparent areas 506 and 507 associated with the barcode, which are notprinted. Alternatively, the background area and the barcode are printedin such colors as to define high contrast therebetween. The barcode inthe first visible state 504 is machine readable in this embodiment andis typically readable by a barcode reader as 7431348787736.

If transparent areas 506 are colored and read together with the barcodein the first visible state 504, there is provided a barcode in a secondvisible state 508 typically readable by a barcode reader as7811348787736. If both transparent areas 506 and 507 are colored andread together with the barcode in the first visible state 504, there isprovided a barcode in a third visible state 509 typically readable by abarcode reader as 7811348782236. There is also a theoretical possibilitythat the transparent areas 507 could be colored and 506 could not becolored, but it is not practical in the present embodiment.

Disposed behind the transparent areas 507 extending perpendicular to thebarcode and preferably adhered to barcode defining layer 502 is acolorable element 510, such as Whatman No. 3 filter paper, commerciallyavailable from Whatman [CAT#: 1003917], which until colored is normallywhite. Disposed behind the barcode defining layer 502 and behind thecolorable element 510 and preferably adhered thereto is a dissolvableactivation delay layer 511 formed, for example from Ethyl Cellulose[CAS#: 9004-57-3]. The activation delay layer 511 is dissolvable by asuitable solvent, as described hereinbelow, and until dissolved preventsthe passage therethrough of coloring agents employed in this embodimentof the present invention.

It is appreciated that the dissolvable activation delay layers 511 mayprovide selectable and possible different delay durations over anysuitable range of durations which may extend from effectively zero toany suitable maximum. Such selectability may be effected, for example,by varying thickness, material, coatings and/or structure.

Disposed behind the activation delay layer 511 is a pull strip 512,corresponding to the pull strip 206 in FIG. 2A, and the pull strip 322in FIG. 3B. The pull strip 512 is preferably white and prevents thepassage therethrough of coloring agents and solvents employed in thisembodiment of the invention. Preferably, the pull strip 512 is formed ofpolyester, for example Melinex® 401, commercially available from DuPontof Wilmington, Del., and is preferably 75 micrometers thick.

Disposed behind the pull strip 512 is a back layer 513 to which ispreferably adhered, rearwardly of the colorable element 510 and of theactivation delay layer 511 but not rearwardly of the barcode, atemperature responsive coloring element 514, such as a pad, for example,K-R; 210/34/28, commercially available from Noam-Urim of Kibbutz Urim,Israel, impregnated with a coloring agent, such as Sudan Black, a blackcolor dye [CAS: 4197-25-5], dissolved at a ratio of 1 gram per 1 kg in asolution of 74.25% Coconut oil [CAS: 8001-31-8], 24.75% Oleic acid [CAS:112-80-1] and 1% Hexanoic acid [CAS: 142-62-1].

Adjacent the coloring element 514 or combined therewith is a solvent515, such as Methyl laurate [CAS #: 111-82-0] which, as noted above, isoperative to dissolve the dissolvable activation delay layer 511,preferably after a predetermined period of time, which is preferablymeasured in hours, such as eight hours. The solvent 515 may betemperature-responsive.

A colored area 516 is formed on the back layer 513, rearwardly of thetransparent areas 506, in order to define high contrast with the barcodedefining layer 502, when the pull strip 512 is removed.

Until such time as the pull strip 512 is removed, the quality indicator500 is nonresponsive to temperature changes and remains in the firstvisible state 504.

Turning now to FIG. 5B, once the pull strip 512 is removed, the solvent515 begins to dissolve the dissolvable activation delay layer 511. Priorto the dissolvable activation delay layer 511 becoming permeable to thecoloring agent in the temperature responsive coloring element 514, thequality indicator 500 does not provide a readable indication responsiveto temperature changes and the portions of the colored area 516 whichare visible through the transparent areas 506 appear similar to the barsof the barcode in the first visible state 504 and can be read togethertherewith as a single barcode in the second visible state 508. It isappreciated that the time needed to achieve dissolution of dissolvableactivation delay layer 511 may be determined for example by thethickness thereof.

Turning now to FIG. 5C, once the dissolvable activation delay layer 511becomes permeable to the coloring agent in the temperature responsivecoloring element 514, typically after 8 hours, the quality indicator 500becomes responsive to temperature changes. As long as the temperature atthe quality indicator does not reach a predetermined temperature forexample 21 degrees Celsius, for at least a predetermined cumulativeamount of time for example for one hour, the quality indicator remainsin the second visible state 508.

Turning now to FIG. 5D, when the temperature at the quality indicatorreaches the predetermined temperature, typically 21 degrees Celsius, thecoloring agent in the coloring element 514 begins to melt and bereleased from the coloring element 514 and begins to diffuse through thecolorable element 510.

It is appreciated that if the temperature thereafter drops below 21degrees Celsius the coloring agent continues to diffuse through thecolorable element 510. If, after the temperature reaches 21 degreesCelsius, the temperature drops below 17 degrees Celsius, the coloringagent becomes solid and diffusion thereof through the colorable element510 is suspended until the temperature again reaches 21 degrees Celsius.

It is appreciated that the elapsed time from the start of diffusion ofthe coloring agent from coloring element 514 along the colorable element510 until portions of the colorable element 510 which are visiblethrough the transparent areas 507 start to become colored is defined forexample by the length of the colorable element 510 between the area infront of the coloring element 514 and the area underlying thetransparent areas 507. Additionally, this elapsed time is a function ofthe material from which the colorable element 510 is made.

As seen in FIG. 5E, when the temperature is at least 21 degrees Celsiusfor at least a predetermined cumulative amount of time, such as 21degrees Celsius for fifty minutes, the coloring agent diffuses throughthe colorable element 510, such that the portions of the colorableelement 510 which are visible through the transparent areas 507 start tobecome colored and appear similar to the bars of the barcode in thefirst visible state 504. It is appreciated that since the direction ofdiffusion of the coloring agent through the colorable element 510underlying the barcode is perpendicular to the barcode, as indicated byreference numeral 517, portions of the barcode in the transparent areas507 can be read together with the barcode in the first visible state 504and with the transparent areas 506 as a single barcode even before thecolorable element 510 is fully colored by the coloring agent.

The portions of the barcode in the transparent areas 507 which arecolored and appear similar to the bars of the barcode in the firstvisible state 504 can be read together therewith and with thetransparent areas 506 as a single barcode in the third visible state509. The portions of the barcode in the transparent areas 507 which arenot colored and do not appear similar to the bars of the barcode in thefirst visible state 504 can be read together with the transparent areas506 as a single barcode in the second visible state 508. Thus it isappreciated that normally at all times following actuation, a readablebarcode is present.

It is appreciated that the appearance of the quality indicator 500during the transition illustrated in FIG. 5E may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 500 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 5F, following the elapse of an additional amount oftime at a temperature of at least 21 degrees Celsius, typically 10minutes, the coloring agent is fully diffused through the colorableelement 510. Consequently, all portions of the colorable element 510which are visible through the transparent areas 507 are colored andappear similar to the bars of the barcode in the first visible state504, and can be read together therewith and with the transparent areas506 as a single barcode in the third visible state 509.

Reference is now made to FIGS. 6A-6F, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator 341 of FIG. 3C for separately indicating elapsed timeand temperature history. As seen in FIG. 6A, the quality indicator, heredesignated by reference numeral 600, preferably includes a barcodedefining layer 602, which is preferably printed on a transparentsubstrate. The printing on the transparent substrate preferably definesa background area, which is preferably printed in a white color, abarcode in a first visible state 604 which is preferably printed in ablack color, and a plurality of transparent areas 606, 607, 608 and 609associated with the barcode, which are not printed. Alternatively, thebackground area and the barcode are printed in such colors as to definehigh contrast therebetween. The barcode in the first visible state 604is machine readable in this embodiment and is typically readable by abarcode reader as 7431348787736.

If the transparent areas 606 are colored and read together with thebarcode in the first visible state 604, there is provided a barcode in asecond visible state 610 typically readable by a barcode reader as7811348787736. If both transparent areas 606 and 609 are colored andread together with the barcode in the first visible state 604, there isprovided a barcode in a third visible state 611 typically readable by abarcode reader as 7811348782236. If the transparent areas 606, 607 and609 are colored and read together with the barcode in the first visiblestate 604, there is provided a barcode in a fourth visible state 612typically readable by a barcode reader as 7817548782236. If thetransparent areas 606, 607, 608 and 609 are colored and read togetherwith the barcode in the first visible state 604, there is provided abarcode in a fifth visible state 613 typically readable by a barcodereader as 7817562782236.

There is also a theoretical possibility that any of the transparentareas 607, 608 and 609 could be colored and the transparent areas 606could not be colored, but it is not practical in the present embodiment.There is an additional theoretical possibility that the transparentareas 608 could be colored and the transparent areas 607 could not becolored, but this in not practical in the present embodiment. It is alsopossible that a combination of transparent areas which is not presentedin the present embodiment will be colored

Disposed behind the transparent areas 609 extending perpendicular to thebarcode and preferably adhered to the barcode defining layer 602 is acolorable element 615, such as Whatman No. 3 filter paper, commerciallyavailable from Whatman [CAT#: 1003917], which until colored is normallywhite. Disposed behind the transparent areas 607 and 608 and extendingin a generally serpentine arrangement mainly in areas not lying behindthe barcode and preferably adhered to the barcode defining layer 602 isa colorable element 616, such as Whatman No. 3 filter paper,commercially available from Whatman [CAT#: 1003917], which until coloredis also normally white. Disposed behind the barcode defining layer 602and behind the colorable elements 615 and 616 is a pull strip 620,corresponding to the pull strip 106 in FIG. 1A, and the pull strip 342in FIG. 3C. The pull strip 620 is preferably white and prevents thepassage therethrough of coloring agents employed in this embodiment ofthe invention. Preferably, the pull strip 620 is formed of polyester,for example Melinex® 401, commercially available from DuPont ofWilmington, Del., and is preferably 75 micrometers thick.

Disposed behind the pull strip 620 is a back layer 621 to which ispreferably adhered, rearwardly of the colorable element 615 but notrearwardly of the barcode, a temperature responsive coloring element623. Also preferably adhered to the back layer 621, rearwardly of thecolorable element 616 but not rearwardly of the barcode, is a coloringelement 625, which is not temperature responsive in its operativetemperature range. The coloring element 623 may be for example a pad,for example, K-R; 210/34/28, commercially available from Noam-Urim ofKibbutz Urim, Israel, impregnated with a coloring agent, such as SudanBlack, a black color dye [CAS: 4197-25-5], dissolved at a ratio of 1gram per 1 kg in Coconut oil [CAS: 8001-31-8]. The coloring element 625may be for example a pad, for example, K-R; 210/34/28, commerciallyavailable from Noam-Urim of Kibbutz Urim, Israel, impregnated with acoloring agent such as Sudan Black, a black color dye [CAS: 4197-25-5],dissolved at a ratio of 1 gram per 1 kg in Methyl laurate [CAS #:111-82-0].

A colored area 627 is formed on the back layer 621, rearwardly of thetransparent areas 606, in order to define high contrast with the barcodedefining layer 602, when the pull strip 620 is removed.

Until such time as the pull strip 620 is removed, the quality indicator600 is nonresponsive to temperature changes and elapsed time and remainsin the first visible state 604.

Turning to FIG. 6B, once the pull strip 620 is removed, the qualityindicator 600 becomes responsive to temperature changes and elapsedtime. As long as the temperature at the quality indicator does notexceed a predetermined temperature, for example 21 degrees Celsius, forat least a predetermined cumulative amount of time, typically one hour,and a predetermined amount of time, typically seven days, has notelapsed since actuation of the indicator, the portions of the coloredarea 627 which are visible through the transparent areas 606 appearsimilar to the bars of the barcode in the first visible state 604 andcan be read together therewith as a single barcode in the second visiblestate 610.

Following removal of the pull strip 620 the coloring agent in thecoloring element 625, which is not temperature responsive in itsoperative temperature range, starts to diffuse through the colorableelement 616.

Turning now to FIG. 6C, following removal of the pull strip 620 and oncethe temperature reaches the predetermined temperature, for example 21degrees Celsius, for at least a predetermined cumulative amount of time,for example for one hour, the coloring agent in the coloring element 623melts and is released from coloring element 623 and rapidly diffusesthrough the colorable element 615, such that the portions of thecolorable element 615 which are visible through the transparent areas609 become colored and appear similar to the bars of the barcode in thefirst visible state 604 and can be read together therewith and withareas 606 as a single barcode as in the third visible state 611.

It is appreciated that if, before the elapse of the predetermined amountof time the temperature drops below 21 degrees Celsius the coloringagent continues to diffuse through the colorable element 615. If, afterthe temperature reaches 21 degrees Celsius, the temperature drops below17 degrees Celsius, the coloring agent becomes solid and diffusionthereof through the colorable element 615 is suspended until thetemperature again reaches 21 degrees Celsius.

It is further appreciated that the elapsed time from the start ofdiffusion of the coloring agent from the coloring element 623 along thecolorable element 615 until portions of the colorable element 615 whichare visible through the transparent areas 609 start to become colored isdefined for example by the length of the colorable element 615 betweenthe area in front of the coloring element 623 and the area underlyingthe transparent areas 609. Additionally, this elapsed time is a functionof the material from which the colorable element 615 is made.

It is also appreciated that the elapsed time from the start of diffusionof the coloring agent from the coloring element 625 along the colorableelement 616 until portions of the colorable element 616 which arevisible through the transparent areas 607 and 608 start to becomecolored is defined for example by the length of the colorable element616 between the area in front of the coloring element 625 and the areaunderlying the transparent areas 607 and 608. Additionally, this elapsedtime is a function of the material from which the colorable element 616is made.

It is further appreciated that the length of the colorable element 616that leads to the transparent areas 608 may be greater than the lengthof the colorable element 616 that leads to the transparent areas 607,and correspondingly the time taken for the coloring agent in thecoloring element 625 to reach the transparent areas 608 may be longerthan the time required for the coloring agent to reach the transparentareas 607.

As seen in FIG. 6D, after the elapse of a predetermined amount of time,typically seven days, since removal of the pull strip 620, the coloringagent diffuses through the colorable element 616, such that the portionsof the colorable element 616 which are visible through the transparentareas 607 start to become colored and appear similar to the bars of thebarcode in the first visible state 604. It is appreciated that since thedirection of diffusion of the coloring agent through the colorableelement 616 underlying the barcode is perpendicular to the barcode, asindicated by reference numeral 630, portions of the barcode in areas 607can be read together with the barcode in the first visible state 604 andwith the transparent areas 606 and 609 as a single barcode even beforethe colorable element 616 is fully colored by the coloring agent.

The portions of the barcode in the transparent areas 607 which arecolored and appear similar to the bars of the barcode in the firstvisible state 604 can be read together therewith and with thetransparent areas 606 and 609 as a single barcode in the fourth visiblestate 612. The portions of the barcode in the transparent areas 607which are not colored and do not appear similar to the bars of thebarcode in the first visible state 604 can be read together with thetransparent areas 606 and 609 as a single barcode in the third visiblestate 611. Thus it is appreciated that normally at all times followingactuation, a readable barcode is present.

It is appreciated that the appearance of the quality indicator 600during the transition illustrated in FIG. 6D may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 600 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 6E, following the elapse of an additional amount oftime, typically 10 minutes, the coloring agent is fully diffused throughthe portion of the colorable element 616 which leads to the transparentareas 607. Consequently, all portions of the colorable element 616 whichare visible through the transparent areas 607 are colored and appearsimilar to the bars of the barcode in the first visible state 604, andcan be read together therewith and with areas 606 and 609 as a singlebarcode in the fourth visible state 612.

Turning to FIG. 6F, after the elapse of an additional predeterminedamount of time, typically another seven days, the coloring agent in thecoloring element 625 is fully diffused through the colorable element616. Consequently, the portions of the colorable element 616 which arevisible through the transparent areas 608 are colored and appear similarto the bars of the barcode in the first visible state 604, and can beread together therewith and with areas 606, 607 and 609 as a singlebarcode as in the fifth visible state 613. It is appreciated thatnormally at all times following actuation, a readable barcode ispresent.

Reference is now made to FIGS. 7A-7G, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator 361 of FIG. 3D separately indicating elapsed time andtemperature history. As seen in FIG. 7A, the quality indicator, heredesignated by reference numeral 700, preferably includes a barcodedefining layer 702, which is preferably printed on a transparentsubstrate. The printing on the transparent substrate preferably definesa background area, which is preferably printed in a white color, abarcode in a first visible state 704 which is preferably printed in ablack color, and a plurality of transparent areas 706, 707, 708 and 709associated with the barcode, which are not printed. Alternatively, thebackground area and the barcode are printed in such colors as to definehigh contrast therebetween. The barcode in the first visible state 704is machine readable in this embodiment and is typically readable by abarcode reader as 7431348787736.

If the transparent areas 706 are colored and read together with thebarcode in the first visible state 704, there is provided a barcode in asecond visible state 710 typically readable by a barcode reader as7811348787736. If both transparent areas 706 and 709 are colored andread together with the barcode in the first visible state 704, there isprovided a barcode in a third visible state 711 typically readable by abarcode reader as 7811348782236. If the transparent areas 706, 707 and709 are colored and read together with the barcode in the first visiblestate 704, there is provided a barcode in a fourth visible state 712typically readable by a barcode reader as 7817548782236. If thetransparent areas 706, 707, 708 and 709 are colored and read togetherwith the barcode in the first visible state 704, there is provided abarcode in a fifth visible state 713 typically readable by a barcodereader as 7817562782236.

There is also a theoretical possibility that any of the transparentareas 707, 708 and 709 could be colored and the transparent areas 706could not be colored, but it is not practical in the present embodiment.There is an additional theoretical possibility that the transparentareas 708 could be colored and the transparent areas 707 could not becolored, but this in not practical in the present embodiment. It is alsopossible that a combination of transparent areas which is not presentedin the present embodiment will be colored.

Disposed behind the transparent areas 709 extending perpendicular to thebarcode and preferably adhered to the barcode defining layer 702 is acolorable element 715, such as Whatman No. 3 filter paper, commerciallyavailable from Whatman [CAT#: 1003917], which until colored is normallywhite. Disposed behind the transparent areas 707 and 708 and extendingin a generally serpentine arrangement mainly in areas not lying behindthe barcode and preferably adhered to the barcode defining layer 702 isa colorable element 716, such as Whatman No. 3 filter paper,commercially available from Whatman [CAT#: 1003917], which until coloredis also normally white. Disposed behind the barcode defining layer 702and behind the colorable element 715 and preferably adhered thereto is adissolvable activation delay layer 717 formed, for example from EthylCellulose [CAS#: 9004-57-3]. Disposed behind the barcode defining layer702 and behind the colorable element 716 and preferably adhered theretois a dissolvable activation delay layer 718 formed, for example fromEthyl Cellulose [CAS#: 9004-57-3]. The dissolvable activation delaylayers 717 and 718 are dissolvable by suitable solvents, as describedhereinbelow, and until dissolved prevent the passage therethrough ofcoloring agents employed in this embodiment of the present invention.

It is appreciated that one or both dissolvable activation delay layers717 and 718 may provide selectable and possible different delaydurations over any suitable range of durations which may extend fromeffectively zero to any suitable maximum. Such selectability may beeffected, for example, by varying thickness, material, coatings and/orstructure.

Disposed behind the dissolvable activation delay layers 717 and 718 is apull strip 720, corresponding to the pull strip 206 in FIG. 2A, and thepull strip 362 in FIG. 3D. The pull strip 720 is preferably white andprevents the passage therethrough of coloring agents and solventsemployed in this embodiment of the invention. Preferably, the pull strip720 is formed of polyester, for example Melinex® 401, commerciallyavailable from DuPont of Wilmington, Del., and is preferably 75micrometers thick.

Disposed behind the pull strip 720 is a back layer 721 to which ispreferably adhered, rearwardly of the colorable element 715 and of theactivation delay layer 717 but not rearwardly of the barcode, atemperature responsive coloring element 723. Also preferably adhered tothe back layer 721, rearwardly of the colorable element 716 and of theactivation delay layer 718 and preferably not rearwardly of the barcode,is a coloring element 725 which is not temperature responsive in itsoperative temperature range. The coloring element 723 may be for examplea pad, for example, K-R; 210/34/28, commercially available fromNoam-Urim of Kibbutz Urim, Israel, impregnated with a coloring agent,such as Sudan Black, a black color dye [CAS: 4197-25-5], dissolved at aratio of 1 gram per 1 kg in Coconut oil [CAS: 8001-31-8]. The coloringelement 725 may be for example a pad, for example, K-R; 210/34/28,commercially available from Noam-Urim of Kibbutz Urim, Israel,impregnated with a coloring agent such as Sudan Black, a black color dye[CAS: 4197-25-5], dissolved at a ratio of 1 gram per 1 kg in Methyllaurate [CAS #: 111-82-0].

Adjacent the coloring element 723 or combined therewith is a solvent726. Adjacent the coloring element 725 or combined therewith is asolvent 727. The solvents 726 and 727 may be for example Methyl laurate[CAS #: 111-82-0], which, as noted above, are operative to dissolve thedissolvable activation delay layers 717 and 718, preferably after apredetermined period of time, which is preferably measured in hours,such as eight hours. Any of the solvents 726 and 727 may be temperatureresponsive.

A colored area 728 is formed on the back layer 721, rearwardly of thetransparent areas 706, in order to define high contrast with the barcodedefining layer 702, when the pull strip 720 is removed.

Until such time as the pull strip 720 is removed, the quality indicator700 is nonresponsive to temperature changes and elapsed time and remainsin the first visible state 704.

Turning to FIG. 7B, once the pull strip 720 is removed, the solvents 726and 727 begin to dissolve the respective dissolvable activation delaylayers 717 and 718. Prior to dissolvable activation delay layers 717 and718 becoming permeable to the coloring agents in the coloring elements723 and 725, the quality indicator 700 does not provide a readableindication responsive to temperature changes and elapsed time and theportions of the colored area 728 which are visible through thetransparent areas 706 are colored and appear similar to the bars of thebarcode in the first visible state 704 and can be read togethertherewith as a single barcode in the second visible state 710. It isappreciated that the time needed to achieve dissolution of dissolvableactivation delay layers 717 and 718 may be determined for example by thethickness thereof.

Turning to FIG. 7C, once the dissolvable activation delay layers 717 and718 become permeable to the coloring agents in the coloring elements 723and 725, typically after 8 hours, the quality indicator 700 becomesresponsive to temperature changes and elapsed time, and the coloringagent in the coloring element 725, which is not temperature responsivein its operative temperature range, starts to diffuse through thecolorable element 716.

Turning to FIG. 7D, once the temperature reaches a predeterminedtemperature, for example 21 degrees, for at least a predeterminedcumulative amount of time, for example for one hour, the temperatureresponsive coloring agent in the coloring element 723 melts and isreleased from the coloring element 723 and rapidly diffuses through thecolorable element 715, such that the portions of the colorable element715 which are visible through the transparent areas 709 are colored andappear similar to the bars of the barcode in the first visible state 704and can be read together therewith and with the transparent areas 706 asa single barcode as in the third visible state 711.

It is appreciated that if, before the elapse of the predetermined amountof time the temperature drops below 21 degrees Celsius the coloringagent continues to diffuse through the colorable element 715. If, afterthe temperature reaches 21 degrees Celsius, the temperature drops below17 degrees Celsius, the coloring agent becomes solid and diffusionthereof through the colorable element 715 is suspended until thetemperature again reaches 21 degrees Celsius.

It is further appreciated that the elapsed time from the start ofdiffusion of the coloring agent from the coloring element 723 along thecolorable element 715 until portions of the colorable element 715 whichare visible through the transparent areas 709 start to become colored isdefined for example by the length of the colorable element 715 betweenthe area in front of the coloring element 723 and the area underlyingthe transparent areas 709. Additionally, this elapsed time is a functionof the material from which the colorable element 715 is made.

It is also appreciated that the elapsed time from the start of diffusionof the coloring agent from the coloring element 725 along the colorableelement 716 until portions of the colorable element 716 which arevisible through the transparent areas 707 and 708 start to becomecolored is defined for example by the length of the colorable element716 between the area in front of the coloring element 725 and the areaunderlying the transparent areas 707 and 708. Additionally, this elapsedtime is a function of the material from which the colorable element 716is made.

It is further appreciated that the length of the colorable element 716that leads to the transparent areas 708 may be greater than the lengthof the colorable element 716 that leads to the transparent areas 707,and correspondingly the time taken for the coloring agent in thecoloring element 725 to reach the transparent areas 708 may be longerthan the time required for the coloring agent to reach the transparentareas 707.

Turning to FIG. 7E, after the elapse of a predetermined amount of time,typically seven days, since dissolution of the activation delay layer718, the coloring agent diffuses through the colorable element 716, suchthat the portions of the colorable element 716 which are visible throughthe transparent areas 707 start to become colored and appear similar tothe bars of the barcode in the first visible state 704. It isappreciated that since the direction of diffusion of the coloring agentthrough the colorable element 716 underlying the barcode isperpendicular to the barcode, as indicated by reference numeral 730,portions of the barcode in the transparent areas 707 can be readtogether with the barcode in the first visible state 704 and with thetransparent areas 706 and 709 as a single barcode even before thecolorable element 716 is fully colored by the coloring agent.

The portions of the barcode in the transparent areas 707 which arecolored and appear similar to the bars of the barcode in the firstvisible state 704 can be read together therewith and with thetransparent areas 706 and 709 as a single barcode in the fourth visiblestate 712. The portions of the barcode in the transparent areas 707which are not colored and do not appear similar to the bars of thebarcode in the first visible state 704 can be read together with thetransparent areas 706 and 709 as a single barcode in the third visiblestate 711. Thus it is appreciated that normally at all times followingactuation, a readable barcode is present.

It is appreciated that the appearance of the quality indicator 700during the transition illustrated in FIG. 7E may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 700 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 7F, following the elapse of an additional amount oftime, typically 10 minutes, the coloring agent is fully diffused throughthe portion of the colorable element 716 which leads to the transparentareas 707. Consequently, all portions of the colorable element 716 whichare visible through the transparent areas 707 are colored and appearsimilar to the bars of the barcode in the first visible state 704, andcan be read together therewith and with the transparent areas 706 and709 as a single barcode in the fourth visible state 712.

Turning to FIG. 7G, after the elapse of an additional predeterminedamount of time, typically another seven days, the coloring agent in thecoloring element 725 is fully diffused through the colorable element716. Consequently, the portions of the colorable element 716 which arevisible through the transparent areas 708 are colored and appear similarto the bars of the barcode in the first visible state 704 and can beread together therewith and with the transparent areas 706, 707 and 709as a single barcode as in the fifth visible state 713. It is appreciatedthat normally at all times following actuation, a readable barcode ispresent.

Reference is now made to FIGS. 8A-9G, which, respectively, aresimplified illustrations of the structure and operation of additionalexamples of quality indicators constructed and operative in accordancewith another preferred embodiment of the present invention forindicating a combination of temperature history and elapsed time.

Reference is now made to FIGS. 8A-8F, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator of the present invention for indicating time intemperature history.

As seen in FIG. 8A, the quality indicator, here designated by referencenumeral 800, preferably includes a barcode defining layer 802, which ispreferably printed on a transparent substrate. The printing on thetransparent substrate preferably defines a background area, a barcode ina first visible state 804, and a plurality of transparent areas 806, 807and 808 associated with the barcode. In accordance with a preferredembodiment of the present invention, which is described in detailhereinbelow with reference to FIG. 10, the barcode defining layer 802 isprinted on a multilayer transparent substrate. In this preferredembodiment, one of the layers is printed with black ink in all areasother than the transparent areas, and is overprinted with white ink inall areas other than the transparent areas and the bars of the barcodein the first visible state, such that the white ink layer faces forwardin the sense of FIG. 8A. The transparent areas are preferably printedwith light blue ink, preferably Pantone No. 645, which has a visualappearance similar to that of the black ink overprinted with white ink.

Alternatively, the background area and the barcode are printed in othercolors as to define high contrast therebetween. The barcode in the firstvisible state 804 is machine readable in this embodiment and istypically readable by a barcode reader as 7431348787736.

If the transparent areas 806 are colored and read together with thebarcode in the first visible state 804, there is provided a barcode in asecond visible state 810 typically readable by a barcode reader as7811348787736. If both transparent areas 806 and 807 are colored andread together with the barcode in the first visible state 804, there isprovided a barcode in a third visible state 811 typically readable by abarcode reader as 7817548787736. If the transparent areas 806, 807 and808 are colored and read together with the barcode in the first visiblestate 804, there is provided a barcode in a fourth visible state 812typically readable by a barcode reader as 78175782236. There is also atheoretical possibility that the transparent areas 807 or 808 could becolored and the transparent areas 806 could not be colored, but it isnot practical in the present embodiment. It is also possible that acombination of transparent areas which are not colored together in thepresent embodiment will be colored.

Disposed behind the transparent areas 808 extending perpendicular to thebarcode and preferably adhered to the barcode defining layer 802 is acolorable element 815, such as Whatman No. 3 filter paper, commerciallyavailable from Whatman [CAT#: 1003917], which until colored is normallywhite. Disposed behind the transparent areas 807 extending perpendicularto the barcode and preferably adhered to the barcode defining layer 802is a colorable element 816, such as Whatman No. 3 filter paper,commercially available from Whatman [CAT#: 1003917], which until coloredis also normally white.

Disposed behind the barcode defining layer 802 and behind the colorableelements 815 and 816 is a pull strip 820. The pull strip 820 ispreferably white and prevents the passage therethrough of coloringagents employed in this embodiment of the invention. Alternatively, thepull strip 820 is transparent. Preferably, the pull strip 820 is formedof polyester, for example Melinex® 401, commercially available fromDuPont of Wilmington, Del. The pull strip 820 is preferably 75micrometers thick and is preferably bifurcated as illustrated.

Disposed behind the pull strip 820 is a back layer 821 which ispreferably black, and to which is preferably adhered, rearwardly of thecolorable element 815 but not rearwardly of the barcode, a temperatureresponsive coloring element 823. Also preferably adhered to the backlayer 821, rearwardly of the colorable element 816 but not rearwardly ofthe barcode, is another temperature responsive coloring element 825.

The coloring element 823 may be, for example, a pad, for example, K-R;210/34/28, commercially available from Noam-Urim of Kibbutz Urim,Israel, impregnated with a coloring agent, such as Sudan Black, a blackcolor dye [CAS: 4197-25-5], dissolved at a ratio of 1 gram per 1 kg inCoconut oil [CAS: 8001-31-8]. The coloring element 825 may be forexample a pad, for example, K-R; 210/34/28, commercially available fromNoam-Urim of Kibbutz Urim, Israel, impregnated with a coloring agent,such as Sudan Black, a black color dye [CAS: 4197-25-5], dissolved at aratio of 1 gram per 1 kg in a solution of 25% Coconut oil [CAS:8001-31-8] and 75% Oleic acid [CAS: 112-80-1].

The colorable element 815 and the coloring element 823 are preferablyseparated from the colorable element 816 and the coloring element 825 bya partition 827 which does not allow the coloring agent from thecoloring element 823 to color the colorable element 816 or the coloringagent from the coloring element 825 to color the colorable element 815.The pull strip 820 is bifurcated in order to accommodate the partition827.

It is appreciated that the length of the colorable element 816 thatleads to the transparent areas 807 may be greater than the length of thecolorable element 815 that leads to the transparent areas 808, andcorrespondingly the time taken for the coloring agent in the coloringelement 825 to reach the transparent areas 807 may be longer than thetime required for the coloring agent in the coloring element 823 toreach the transparent areas 808.

Until such time as the pull strip 820 is removed, the quality indicator800 is nonresponsive to temperature changes and remains in the firstvisible state 804.

Turning to FIG. 8B, once the pull strip 820 is removed, the qualityindicator 800 becomes responsive to temperature changes. As long as thetemperature at the quality indicator does not reach a predeterminedtemperature, for example 8 degrees Celsius, for at least a predeterminedcumulative amount of time, typically five hours, the portions of theblack background layer 821 which are visible through the transparentareas 806 appear similar to the bars of the barcode in the first visiblestate 804 and can be read together therewith as a single barcode in thesecond visible state 810.

It is appreciated that in accordance with an alternative embodiment ofthe present invention, the pull strip 820 may be transparent and thebarcode may remain in the first visible state 804 after the pull stripis removed.

Turning to FIG. 8C, when the pull strip 820 has been removed and whenthe temperature at the quality indicator reaches 8 degrees Celsius, thecoloring agent in the coloring element 825 begins to melt and bereleased from the coloring element 825 and begins to diffuse through thecolorable element 816. It is appreciated that if the temperaturethereafter drops below 8 degrees Celsius the coloring agent continues todiffuse through the colorable element 816. If, after the temperaturereaches 8 degrees Celsius, the temperature drops below 5 degreesCelsius, the coloring agent becomes solid and diffusion thereof throughthe colorable element 816 is suspended until the temperature againreaches 8 degrees Celsius.

It is appreciated that the elapsed time from the start of diffusion ofthe coloring agent from the coloring element 825 along the colorableelement 816 until portions of the colorable element 816 which arevisible through the transparent areas 807 start to become colored isdefined for example by the length of the colorable element 816 betweenthe area in front of the coloring element 825 and the area underlyingthe transparent areas 807. Additionally, this elapsed time is a functionof the material from which the colorable element 816 is made.

It is also appreciated that the elapsed time from the start of diffusionof the coloring agent from the coloring element 823 along the colorableelement 815 until portions of the colorable element 815 which arevisible through the transparent areas 808 start to become colored isdefined for example by the length of the colorable element 815 betweenthe area in front of the coloring element 823 and the area underlyingthe transparent areas 808. Additionally, this elapsed time is a functionof the material from which the colorable element 815 is made.

As seen in FIG. 8D, when the temperature is at least 8 degrees Celsiusfor at least a predetermined cumulative amount of time, such as 8degrees Celsius for four hours and fifty minutes, the coloring agentdiffuses through the colorable element 816, such that the portions ofthe colorable element 816 which are visible through the transparentareas 807 start to become colored and appear similar to the bars of thebarcode in the first visible state 804. It is appreciated that since thedirection of diffusion of the coloring agent through the colorableelement 816 underlying the barcode is perpendicular to the barcode, asindicated by reference numeral 830, portions of the barcode in thetransparent areas 807 can be read together with the barcode in the firstvisible state 804 and with the transparent areas 806 as a single barcodeeven before the colorable element 816 is fully colored by the coloringagent.

The portions of the barcode in the transparent areas 807 which arecolored and appear similar to the bars of the barcode in the firstvisible state 804 can be read together therewith and with areas 806 as asingle barcode in the third visible state 811. The portions of thebarcode in the transparent areas 807 which are not colored and do notappear similar to the bars of the barcode in the first visible state 804can be read together with the transparent areas 806 as a single barcodein the second visible state 810. Thus it is appreciated that normally atall times following actuation, a readable barcode is present.

It is appreciated that the appearance of the quality indicator 800during the transition illustrated in FIG. 8D may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 800 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 8E, it is seen that following the elapse of anadditional amount of time at a temperature of at least 8 degreesCelsius, typically 10 minutes, the coloring agent is fully diffusedthrough colorable element 816. Consequently, all portions of thecolorable element 816 which are visible through the transparent areas807 are colored and appear similar to the bars of the barcode in thefirst visible state 804, and can be read together therewith and withareas 806 as a single barcode in the third visible state 811.

Turning now to FIG. 8F, it is seen that when the temperature is at least21 degrees Celsius for at least a predetermined cumulative amount oftime, such as 21 degrees Celsius for two hours, the coloring agent inthe coloring element 823 is fully diffused through the colorable element815. Consequently, the portions of the colorable element 815 which arevisible through the transparent areas 808 are colored and appear similarto the bars of the barcode in the first visible state 804 and can beread together therewith and with the transparent areas 806 and 807 as asingle barcode as in the fourth visible state 812. It is appreciatedthat normally at all times following actuation, a readable barcode ispresent.

It is appreciated that if, prior to the elapse of the predeterminedamount of time, the temperature drops below 21 degrees Celsius, thecoloring agent continues to diffuse through the colorable element 815.If, after the temperature reaches 21 degrees Celsius, the temperaturedrops below 17 degrees Celsius, the coloring agent becomes solid anddiffusion thereof through the colorable element 815 is suspended untilthe temperature again reaches 21 degrees Celsius.

Reference is now made to FIGS. 9A-9G, which together are a simplifiedillustration of the construction and operation of one embodiment of thequality indicator of the present invention for indicating time intemperature history with delayed activation.

As seen in FIG. 9A, the quality indicator, here designated by referencenumeral 900, preferably includes a barcode defining layer 902, which ispreferably printed on a transparent substrate. The printing on thetransparent substrate preferably defines a background area, a barcode ina first visible state 904, and a plurality of transparent areas 906, 907and 908 associated with the barcode. In accordance with a preferredembodiment of the present invention, which is described in detailhereinbelow with reference to FIG. 10, the barcode defining layer 902 isprinted on a multilayer transparent substrate. In this preferredembodiment, one of the layers is printed with black ink in all areasother than the transparent areas, and is overprinted with white ink inall areas other than the transparent areas and the bars of the barcodein the first visible state, such that the white ink layer faces forwardin the sense of FIG. 9A. The transparent areas are preferably printedwith light blue ink, preferably Pantone No. 645, which has a visualappearance similar to that of the black ink overprinted with white ink.

Alternatively, the background area and the barcode are printed in othercolors as to define high contrast therebetween. The barcode in the firstvisible state 904 is machine readable in this embodiment and istypically readable by a barcode reader as 7431348787736.

If the transparent areas 906 are colored and read together with thebarcode in the first visible state 904, there is provided a barcode in asecond visible state 910 typically readable by a barcode reader as7811348787736. If both transparent areas 906 and 907 are colored andread together with the barcode in the first visible state 904, there isprovided a barcode in a third visible state 911 typically readable by abarcode reader as 7817548787736. If the transparent areas 906, 907 and908 are colored and read together with the barcode in the first visiblestate 904, there is provided a barcode in a fourth visible state 912typically readable by a barcode reader as 78175782236. There is also atheoretical possibility that the transparent areas 907 or 908 could becolored and the transparent areas 906 could not be colored, but it isnot practical in the present embodiment. It is also possible that acombination of transparent areas which are not colored together in thepresent embodiment will be colored.

Disposed behind the transparent areas 908 extending perpendicular to thebarcode and preferably adhered to the barcode defining layer 902 is acolorable element 915, such as Whatman No. 3 filter paper commerciallyavailable from Whatman [CAT#: 1003917], which until colored is normallywhite. Disposed behind the transparent areas 907 extending perpendicularto the barcode and preferably adhered to the barcode defining layer 902is a colorable element 916, such as Whatman No. 3 filter papercommercially available from Whatman [CAT#: 1003917], which until coloredis also normally white.

Disposed behind the barcode defining layer 902 and behind the colorableelement 915 and preferably adhered thereto is a dissolvable activationdelay layer 917, formed, for example from Ethyl Cellulose [CAS#:9004-57-3]. Disposed behind the barcode defining layer 902 and behindthe colorable element 916 and preferably adhered thereto is adissolvable activation delay layer 918, formed, for example from EthylCellulose [CAS#: 9004-57-3].The dissolvable activation delay layers 917and 918 are dissolvable by suitable solvents, as described hereinbelow,and until dissolved prevent the passage therethrough of coloring agentsemployed in this embodiment of the present invention.

It is appreciated that one or both dissolvable activation delay layers917 and 918 may provide selectable and possibly different delaydurations over any suitable range of durations which may extend fromeffectively zero to any suitable maximum. Such selectability may beeffected, for example, by varying thickness, material, coatings and/orstructure.

Disposed behind the dissolvable activation delay layers 917 and 918 is apull strip 920. The pull strip 920 is preferably white and prevents thepassage therethrough of coloring agents and solvents employed in thisembodiment of the invention. Alternatively, the pull strip 920 istransparent. Preferably, the pull strip 920 is formed of polyester, forexample Melinex® 401, commercially available from DuPont of Wilmington,Del. The pull strip 920 is preferably 75 micrometers thick and ispreferably bifurcated as illustrated.

Disposed behind the pull strip 920 is a back layer 921 which ispreferably black, and to which is preferably adhered, rearwardly of thecolorable element 915 and of the activation delay layer 917 but notrearwardly of the barcode, a temperature responsive coloring element923. Also preferably adhered to the back layer 921, rearwardly of thecolorable element 916 and of the activation delay layer 918 but notrearwardly of the barcode, is another temperature responsive coloringelement 925.

The coloring element 923 may be, for example, a pad, for example, K-R;210/34/28, commercially available from Noam-Urim of Kibbutz Urim,Israel, impregnated with a coloring agent, such as Sudan Black, a blackcolor dye [CAS: 4197-25-5], dissolved at a ratio of 1 gram per 1 kg inCoconut oil [CAS: 8001-31-8]. The coloring element 925 may be forexample a pad, for example, K-R; 210/34/28, commercially available fromNoam-Urim of Kibbutz Urim, Israel, impregnated with a coloring agent,such as Sudan Black, a black color dye [CAS: 4197-25-5], dissolved at aratio of 1 gram per 1 kg in a solution of 25% Coconut oil [CAS:8001-31-8] and 75% Oleic acid [CAS: 112-80-1].

The colorable element 915 and the coloring element 923 are preferablyseparated from the colorable element 916 and the coloring element 925 bya partition 927 which does not allow coloring agent from the coloringelement 923 to color the colorable element 916 or coloring agent fromthe coloring element 925 to color the colorable element 915. The pullstrip 920 is bifurcated in order to accommodate the partition 927.

Adjacent the coloring element 923 or combined therewith is a solvent926. Adjacent the coloring element 925 or combined therewith is asolvent 928. The solvents 926 and 928 may be for example Methyl laurate[CAS #: 111-82-0], which, as noted above, are operative to dissolve thedissolvable activation delay layers 917 and 918, preferably after apredetermined period of time, which is preferably measured in hours,such as eight hours.

It is appreciated that the length of the colorable element 916 thatleads to the transparent areas 907 may be greater than the length of thecolorable element 915 that leads to the transparent areas 908, andcorrespondingly the time taken for the coloring agent in the coloringelement 925 to reach the transparent areas 907 may be longer than thetime required for the coloring agent in the coloring element 923 toreach the transparent areas 908.

Until such time as the pull strip 920 is removed, the quality indicator900 is nonresponsive to temperature changes and remains in the firstvisible state 904.

Turning now to FIG. 9B, once the pull strip 920 is removed, the solvents926 and 928 begin to dissolve the respective dissolvable activationdelay layers 917 and 918. Prior to dissolvable activation delay layers917 and 918 becoming permeable to the coloring agents in the respectivetemperature responsive coloring elements 923 and 925, the qualityindicator 900 does not provide a readable indication responsive totemperature changes and the portions of the black background layer 921which are visible through the transparent areas 906 appear similar tothe bars of the barcode in the first visible state 904 and can be readtogether therewith as a single barcode in the second visible state 910.It is appreciated that the time needed to achieve dissolution ofdissolvable activation delay layers 917 and 918 may be determined forexample by the thickness thereof.

It is appreciated that in accordance with an alternative embodiment ofthe present invention, the pull strip 920 may be transparent and thebarcode may remain in the first visible state 904 after the pull stripis removed.

Turning now to FIG. 9C, once the dissolvable activation delay layers 917and 918 become permeable to the coloring agents in the respectivetemperature responsive coloring elements 923 and 925, typically after 8hours, the quality indicator 900 becomes responsive to temperaturechanges. As long as the temperature at the quality indicator does notreach a predetermined temperature for example 8 degrees Celsius, for atleast a predetermined cumulative amount of time for example for fivehours, the quality indicator remains in the second visible state 910.

Turning to FIG. 9D, once the dissolvable activation delay layers 917 and918 become permeable to the coloring agents in the respectivetemperature responsive coloring elements 923 and 925, and when thetemperature at the quality indicator reaches 8 degrees Celsius, thecoloring agent in the coloring element 925 begins to melt and bereleased from coloring element 925 and begins to diffuse through thecolorable element 916. It is appreciated that if the temperaturethereafter drops below 8 degrees Celsius the coloring agent continues todiffuse through the colorable element 916. If, after the temperaturereaches 8 degrees Celsius, the temperature drops below 5 degreesCelsius, the coloring agent becomes solid and diffusion thereof throughthe colorable element 916 is suspended until the temperature againreaches 8 degrees Celsius.

It is appreciated that the elapsed time from the start of diffusion ofthe coloring agent from the coloring element 925 along the colorableelement 916 until portions of the colorable element 916 which arevisible through the transparent areas 907 start to become colored isdefined for example by the length of the colorable element 916 betweenthe area in front of coloring element 925 and the area underlying thetransparent areas 907. Additionally, this elapsed time is a function ofthe material from which the colorable element 916 is made.

It is also appreciated that the elapsed time from the start of diffusionof the coloring agent from the coloring element 923 along the colorableelement 915 until portions of the colorable element 915 which arevisible through the transparent areas 908 start to become colored isdefined for example by the length of the colorable element 915 betweenthe area in front of coloring element 923 and the area underlying thetransparent areas 908. Additionally, this elapsed time is a function ofthe material from which the colorable element 915 is made.

As seen in FIG. 9E, when the temperature is at least 8 degrees Celsiusfor at least a predetermined cumulative amount of time, such as 8degrees Celsius for four hours and fifty minutes, the coloring agentdiffuses through the colorable element 916, such that the portions ofthe colorable element 916 which are visible through the transparentareas 907 start to become colored and appear similar to the bars of thebarcode in the first visible state 904. It is appreciated that since thedirection of diffusion of the coloring agent through the colorableelement 916 underlying the barcode is perpendicular to the barcode, asindicated by reference numeral 930, portions of the barcode in thetransparent areas 907 can be read together with the barcode in the firstvisible state 904 and with the transparent areas 906 as a single barcodeeven before the colorable element 916 is fully colored by the coloringagent.

The portions of the barcode in the transparent areas 907 which arecolored and appear similar to the bars of the barcode in the firstvisible state 904 can be read together therewith and with thetransparent areas 906 as a single barcode in the third visible state911. The portions of the barcode in the transparent areas 907 which arenot colored and do not appear similar to the bars of the barcode in thefirst visible state 904 can be read together with the transparent areas906 as a single barcode in the second visible state 910. Thus it isappreciated that normally at all times following actuation, a readablebarcode is present.

It is appreciated that the appearance of the quality indicator 900during the transition illustrated in FIG. 9E may be somewhat problematicin that two alternative readings are possible. It is neverthelessbelieved that this situation is preferable to a situation wherein thequality indicator 900 is not at all readable during the transition,inter alia since the quality indicator may include portions that are notin transition and further since it is possible to program the indicationinterpreter to prefer an exceedance indication over a subsequently readnon-exceedance indication. It is desirable that the time duration of thetransition be as short as possible.

Turning now to FIG. 9F, it is seen that following the elapse of anadditional amount of time at a temperature of at least 8 degreesCelsius, typically 10 minutes, the coloring agent is fully diffusedthrough the colorable element 916. Consequently, all portions of thecolorable element 916 which are visible through the transparent areas907 are colored and appear similar to the bars of the barcode in thefirst visible state 904, and can be read together therewith and with thetransparent areas 906 as a single barcode in the third visible state911.

Turning now to FIG. 9G, it is seen that when the temperature is at least21 degrees Celsius for at least a predetermined cumulative amount oftime, such as 21 degrees Celsius for two hours, the coloring agent inthe coloring element 923 is fully diffused through the colorable element915. Consequently, the portions of the colorable element 915 which arevisible through the transparent areas 908 are colored and appear similarto the bars of the barcode in the first visible state 904 and can beread together therewith and with the transparent areas 906 and 907 as asingle barcode as in the fourth visible state 912. It is appreciatedthat normally at all times following actuation, a readable barcode ispresent.

It is appreciated that if, prior to the elapse of the predeterminedamount of time, the temperature drops below 21 degrees Celsius, thecoloring agent continues to diffuse through the colorable element 915.If, after the temperature reaches 21 degrees Celsius, the temperaturedrops below 17 degrees Celsius, the coloring agent becomes solid anddiffusion thereof through the colorable element 915 is suspended untilthe temperature again reaches 21 degrees Celsius.

It is appreciated that the present invention also encompasses indicatorswherein the first visible state has more digits than the second visiblestate and similarly where each subsequent visible state has fewer digitsthan the preceding visible state. This may readily be achieved inaccordance with the present invention, for example, by initiallylocating a black background or black colorable elements behindtransparent areas, similar to the transparent areas describedhereinabove with reference to FIGS. 4A-9G, and then, as the result of achange in an environmental parameter, changing that black background orthe black colorable elements to white. Alternatively, this may beachieved by employing white on black background barcodes instead ofblack on white background barcodes as shown in the examples above.

Reference is now made to FIG. 10, which is a more detailed simplifiedillustration of the structure of an example of the quality indicator ofFIGS. 8A-9G.

As seen in FIG. 10, the barcode defining layer in FIG. 8A, thereindicated by reference numeral 802, and the barcode defining layer inFIG. 9A, there indicated by reference numeral 902, includes four layersof plastic, divided into two laminates. The outermost laminate in thesense of FIG. 8A is a transparent adhesive laminate 1002, preferably FASSON, PP NG TOP TRANSPARENT, commercially available from FAS SON ofMentor, Ohio, a division of the Avery Dennison Corporation. It isappreciated that this transparent adhesive laminate is manufactured withan additional layer of silicon, which is removed prior to use in orderto expose an underlying layer of adhesive material. After removal of thesilicon layer, laminate 1002 includes two layers and is 0.066millimeters thick. The outermost layer in the sense of FIG. 8A is alayer 1003, preferably formed of polypropylene, and disposed behindlayer 1003 is an adhesive layer 1004.

Disposed behind laminate 1002 in the sense of FIG. 8A is a 0.2millimeter thick laminate 1005, preferably a layered laminate, such aslayered laminate CAT#: 03166599001, commercially available from MigvanFlexible packaging LTD of Kibbutz Mishmar David, Israel.

Laminate 1005 preferably includes three layers. The outermost layer inthe sense of FIG. 8A is a 24 micrometer thick layer 1006, preferablyformed of polyester. As noted above with reference to FIGS. 8A and 9A,layer 1006 is preferably printed in such a way as to define a backgroundarea 1007, a barcode in the first visible state 1008 and transparentareas 1010. The background area 1007 and the barcode area 1008 areprinted with black ink. The background area 1007 printed with black inkis overprinted with white ink, such that the white ink layer facesforward in the sense of FIG. 8A. The transparent areas 1010 are printedwith light blue ink, Pantone No. 645, which has a visual appearancesimilar to that of the black ink overprinted with white ink. Afterprinting of layer 1006, laminate 1005 is attached to laminate 1002 bythe adhesive layer 1004. Disposed behind layer 1006 of laminate 1005 isan additional 24 micrometer thick layer 1012, preferably formed ofpolyester. Disposed behind layer 1012 is a layer 1014, preferably formedof polyethylene.

It is also seen from FIG. 10 that the back layer indicated in FIG. 8A byreference numeral 821, and in FIG. 9A by reference numeral 921, includesfour layers of plastic divided into two laminates.

The innermost laminate in the sense of FIG. 8A is laminate 1015,preferably a transparent adhesive laminate, commercially available fromMigvan Flexible packaging LTD of Kibbutz Mishmar David, Israel [CAT#:02166599002]. It is appreciated that this transparent adhesive laminateis manufactured with an additional layer of silicon, which is removedprior to use in order to expose a layer of adhesive material. Afterremoval of the silicon layer laminate 1015 includes two layers ofplastic and is 0.09 millimeters thick. The innermost layer in the senseof FIG. 8A is layer 1016, preferably formed of polyethylene, which isused for welding of laminate 1015 to layer 1014 of laminate 1005 alongthe edges and across the quality indicator, as indicated by referencenumeral 1017. The welding across the quality indicator is used to createthe partition indicated by reference numeral 827 in FIG. 8A, and byreference numeral 927 in FIG. 9A.

The pull strip indicated by reference numeral 820 in FIG. 8A and byreference numeral 920 in FIG. 9A, the colorable elements indicated byreference numerals 815 and 816 in FIG. 8A, and by reference numerals 915and 916 in FIG. 9A, the coloring elements indicated by referencenumerals 823 and 825 in FIG. 8A, and by reference numerals 923 and 925in FIG. 9A, the dissolvable activation delay layers indicated byreference numerals 917 and 918 in FIG. 9A, and the solvents indicated byreference numerals 926 and 928 in FIG. 9A are all disposed between layer1014 and layer 1016.

Disposed behind layer 1016 in the sense of FIG. 8A and also part oflaminate 1015 is layer 1018, preferably formed of polypropylene, anddisposed behind layer 1018 is an adhesive layer 1020.

Disposed behind laminate 1015 in the sense of FIG. 8A is a transparentadhesive laminate 1023 0.126 millimeters thick, preferably FASSON, PP NGTOP TRANSPARENT, commercially available from FASSON of Mentor, Ohio, adivision of the Avery Dennison Corporation. Laminate 1023 includes twolayers of plastic. The innermost layer of laminate 1023 in the sense ofFIG. 8A is layer 1024, preferably formed of polypropylene. Layer 1024 ispreferably printed in black. After printing of layer 1024, laminate 1023is attached to laminate 1015 through the adhesive layer 1020 of laminate1015. Disposed behind layer 1024 in the sense of FIG. 8A and also partof laminate 1023 is an adhesive layer 1028. Disposed behind layer 1028is layer 1030, preferably formed of silicon, which prevents adhesivelayer 1028 from adhering to undesired surfaces. Layer 1030 is removedwhen the quality indicator is used in order to attach the qualityindicator to the desired product.

Reference is now made to FIG. 11, which illustrates the structure andoperation of a quality management system constructed and operative inaccordance with a preferred embodiment of the present invention in thecontext of a supermarket. In the embodiment of FIG. 11, packagedproducts 1100 each bear a barcoded quality indicator 1101 of the generaltype described hereinabove and illustrated in FIGS. 1A-9G and includingone or more of the operational and structural features describedhereinabove. As seen in FIG. 11, cartons 1102 including packages 1100bearing quality indicators 1101, bear barcoded quality indicators 1103of the general type described hereinabove and illustrated in FIGS. 1A-9Gand including one or more of the operational and structural featuresdescribed hereinabove. Preferably, the barcoded quality indicators 1103are different from the barcoded quality indicators 1101.

As described hereinabove with reference to FIGS. 1A and 2A, it is aparticular feature of the present invention that the time andtemperature thresholds of the quality indicators 1101 and 1103, placedon the individual packages and the cartons containing them respectively,are preferably related in order to provide highly effective cold chainmanagement.

In the illustrated embodiment, the quality indicators 1101 and 1103preferably include an EAN (European Article Number) barcode. When readby a conventional barcode reader 1104 or by a conventional checkoutscanner 1106, quality indicators 1101 and 1103 provide barcode readerreadable indications of exceedance of one or more thresholds of productquality affecting parameters, such as temperature and/or elapsed timeand/or a combination of elapsed time and temperature to an indicationinterpreter which preferably forms part of or is otherwise connected toa quality indication computer 1108. The quality indication computer 1108may be remote from the indicator reader.

As indicated above with reference to FIGS. 1A-9G, the quality indicator1101 preferably includes a first visible state, typically readable by abarcode reader as 7431348787736, a second visible state, typicallyreadable by a barcode reader as 7811348787736, and a third visiblestate, typically readable by a barcode reader as 7811348782236.

As indicated above with reference to FIGS. 1A-2F, the quality indicator1103 preferably includes a first visible state, typically readable by abarcode reader as 7431348787750, a second visible state, typicallyreadable by a barcode reader as 7437548787750, and a third visiblestate, typically readable by a barcode reader as 7437548782250.

The quality indicators 1101 and 1103 may differ in that they havedifferent effective temperature and/or time thresholds and may alsoindicate exceedance of different quality affecting parameters.

It is further seen in FIG. 11 that in addition to receiving the outputindications provided by the indicator reader the quality indicationcomputer 1108 also receives product-related parameters such as producttype, manufacturing date and package type, as shown in Table II.Additionally or alternatively, the quality indication computer 1108 mayalso receive other parameters, for example information relating to thequality indicator, such as the range of parameters sensed by the qualityindicator, when the quality indicator was actuated, and whether thequality indicator includes a delayed activation feature.

In the illustrated embodiment, product identification information isentered by scanning additional indicators 1110 and 1112, including, forexample, a UPC code, which are attached to packages 1100 and to cartons1102, respectively. Alternatively, the product-related parameters andthe other parameters, such as those relating to the quality indicatormay be provided by the quality indicators 1101 and 1103 themselves. As afurther alternative, these parameters may be provided by sensors, apriori information otherwise available to the indication interpreter orby manual entry.

TABLE II PRODUCT PRODUCT MANUFACTURING PACKAGE CODE DESCRIPTION DATETYPE 6789 FRESH RIB 8 MAY 2008 INDIVIDUAL STEAK

As seen in the illustrated embodiment, the quality indication computer1108 maintains a database which preferably includes at least an eventdescription table, such as Table III, and a product status table, suchas Table IV.

TABLE III EVENT INDICATOR EVENT BAR CODE IDENTIFIER DESCRIPTION7431348787736 1101 INDICATOR WAS NOT ACTUATED 7431348787750 1103INDICATOR WAS NOT ACTUATED 7811348787736 1101 INDICATOR WAS NOT EXPOSEDTO ≥21 DEGREES CELSIUS FOR ≥ONE HOUR 7437548787750 1103 INDICATOR WASNOT EXPOSED TO ≥12 DEGREES CELSIUS FOR ≥FIVE HOURS 7811348782236 1101INDICATOR WAS EXPOSED TO ≥21 DEGREES CELSIUS FOR ≥ONE HOUR 74375487822501103 INDICATOR WAS EXPOSED TO ≥12 DEGREES CELSIUS FOR ≥FIVE HOURS

Upon receipt of inputs identifying a product as shown in Table II andoutput indications provided by a quality indicator reader indicating anevent described in Table III corresponding to the same product thequality indication computer 1108 is operative to provide product qualitystatus outputs. In order to provide product quality status outputs thequality indication computer 1108 is operative to employ a product statustable, such as Table IV, typically including product description datasuch as product description, package type and indicator identifier, anevent barcode and a product status as follows:

TABLE IV PRODUCT EVENT PRODUCT INDICATOR PRODUCT CODE BAR CODE DESCR.PACKAGE IDENTIFIER STATUS 6789 7811348787736 FRESH RIB INDIVIDUAL 1101OK STEAK 6789 7811348782236 FRESH RIB INDIVIDUAL 1101 BAD STEAK 56897437548782250 FRESH RIB CARTON 1103 BAD STEAK 4321 7811348782236 ORANGESINDIVIDUAL 1101 QUICK SALE

As seen in the second and the third rows of Table IV, time andtemperature thresholds of indicators 1101 and 1103, placed on theindividual packages 1100 of a fresh rib steak and the cartons 1102containing them respectively, are preferably related and calibrated withrespect to each other based, inter alia, on empirical data. This featureallows for the evaluation of quality of individually packaged productseven when it is not possible to open the cartons and examine individualpackages, such as for example, during transport.

As further seen in Table IV, there may be a great variation in theeffect of a given event depending on the type of product. Thus, forexample, exposure to 21 degrees Celsius for one hour may cause freshmeat to be rendered unfit for sale but may only mildly affect thequality or oranges.

In accordance with an additional feature of the present invention, thebarcode may be read by a consumer employing an imager-equipped telephoneor other suitable mobile communicator 1115 which may be identical tomobile communicator 128 in FIG. 1C or 228 in FIG. 2C. The communicator1115 may image the quality indicators 1101 or 1103 and communicate theimage information to a suitably programmed quality indication computer1117, which may be identical to computer 130 in FIG. 1C or 230 in FIG.2C, and to the computer 1108, and which is capable of reading thebarcode from the image information. The quality indication computer 1117provides to the user, via SMS or any other suitable communicationmethodology, an immediate indication of a quality status, such as a GOODQUALITY indication 1120. This quality status indicates that the productis safe for use. Alternatively, if the user employs a barcodereader-equipped communicator, the communicator can provide to thequality indication computer 1117 an output resulting from reading thebarcode. Additionally or alternatively, the quality indication computer1117 may provide coupons to the user corresponding to the state of thequality indicator.

Based on the scanned barcode and identification of the caller, thequality indication computer 1117 provides product status informationboth to quality assurance inspectors and to consumers. Additionally oralternatively, the quality indication computer 1117 may send messages tothe supermarket management regarding remedial steps to be taken, such asrefrigeration maintenance instructions.

It will be appreciated by persons skilled in the art that the presentinvention is not limited by what has been particularly shown anddescribed hereinabove. Rather the scope of the present inventionincludes both combinations and sub-combinations of various features ofthe invention and modifications thereof which may occur to personsskilled in the art upon reading the foregoing description and which arenot in the prior art.

1-38. (canceled)
 39. A quality management system for productscomprising: a first multiplicity of individual package specific barcodedquality indicators each operative to provide a machine-readableindication of exceedance of at least one threshold by at least oneproduct quality affecting parameter of an individual package; a secondmultiplicity of outer package specific barcoded quality indicators eachoperative to provide a machine-readable indication of exceedance of atleast one threshold by at least one product quality affecting parameterof an outer package containing a plurality of said individual packages;a barcode indicator reader operative to read said barcoded indicatorsand to provide output indications; and a product type responsiveindication interpreter operative to receive said output indications andto provide human sensible, product quality status outputs. 40-43.(canceled)
 44. A quality management system for products according toclaim 39 and wherein the thresholds for which indication of exceedanceis provided by said outer package specific indicators correspond to anoperative range different from the operative range to which thethresholds for which indication of exceedance is provided by saidindividual package specific indicators correspond.
 45. A qualitymanagement system for products according to claim 44 and whereinindication of exceedance may be provided by said outer package specificindicators associated with outer packages even when indication ofexceedance is not provided by said individual package specificindicators attached to the individual packages contained therein.
 46. Aquality management system for products according to claim 45 and whereinindication of exceedance is not provided by said individual packagespecific indicators associated with individual packages if an indicationof exceedance was not provided by said outer package specific indicatorsassociated with the outer packages containing them.